水华蓝藻热化学催化液化制备生物燃料的分析-analysis on preparation of biofuel by thermochemical catalytic liquefaction of cyanobacteria bloom.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 Abstract Harmful algal blooms frequently occur in aquatic systems and pose serious risks for human and animal health. Among all solutions for algal blooms disposal and resource utilization, one of the most promising methods is that harvesting and using algal biomass as fuel. From an economic point of view, fuel production from algae requires utilization of the complete biomass as efficiently as possible. This thesis aims at transforming bloom-forming cyanobacteria (BC) into biofuel by thermochemical catalytic conversion, for the sake of achieving economic, social and environmental common development. The performance of bloom-forming cyanobacteria (BC) pyrolysis was studied by Thermogravimetry-derivative thermogravimetry (TG/DTG) analysis, from room temperature to 900℃ under different heating rates（5、10、20 and 40℃/min）. Results showed that three stages appeared in the pyrolysis process with increasing temperature, they are water precipitation, volatiles precipitation and carbonization, separately. The kinetic analysis was performed by using the iso-conversional method and the principal-curves method，the kinetic parameters, such as apparent energy of activation Ea, the pyrolysis exponent n and pre-exponential factor A, were determined. The liquefaction conditions were optimized by Response Surface Methodology and Design-Expert software analysis as follows: the concentrated sulfuric acid content was 6.6%, the temperature was 175℃ ， the time was 30 min and the ratio of material to solution was 1:4. The conversion yield and oil yield (chloroform phase) reached 94.85% and 37.96% at above-mentioned conditions. The elemental analysis and calorific value of the oil were determined, and the chemical composition of the oil was investigated using gas chromatography-mass spectroscopy (GC-MS) technique, Fourier-transform infrared (FT-IR) spectroscopy and carbon 13 nuclear magnetic resonance （ 1