水化硅酸钙—植物系统对底泥磷迁移转化的影响机制研究-study on the influence mechanism of calcium silicate hydrate - plant system on phosphorus transport and transformation in sediment.docxVIP

但植物对水体pH的变化能起到缓冲作用，使上覆水pH值基本维持在8.5~8.9。反过来，pH的升高又能够提高晶析除磷的效果，促进结晶反应的持续进行。实验证明，较高的pH是水化硅酸钙起到控磷效果的条件。关键词：水化硅酸钙，结晶除磷，穗状狐尾藻，富营养化，底泥磷形态ABSTRACTEutrophicationisacrucialprobleminourmodernsociety.Sincephosphoroushasbeenconsideredthemainfactorofeutrophicationandaccumulationofendogenousphosphorousinsedimentwhichhasbroughtahugepotentialrisktolakeeutrophication,itisaessentialtoreducetheamountofendogenousphosphorousandcontrolitsreleasefromthesediment.Thephytoremediationhasbeenwidelyusedinendogenousphosphorouscontrolinrecentyears.However,problemsoflowremediationefficiencyhavegraduallycomeoutinsomepracticalapplications.Inordertoenhancetheefficiency,anewly-developedphosphorusremovalmaterial,CalciumSilicateHydrates(CSH)isappliedinthephytoremediationastheseedofcrystallization,whichcanalsopromotethegrowthofplantsandimprovetocontroltheendogenousphosphorousreleasingfromthesediment.Inthispaper,thephosphorousremovalabilityofthisnewly-developedmaterialCSHanditsprinciplewerestudied,withtheeffecttocontrolthephosphorousreleasingfromthesediment.PhosphorousfromsedimentwasexaminedtoanalyzetheinfluenceofCSHonphosphoroustransformationinsediment.Onthebasis,crystallizationwascombinedwithphytoremediation.TheeffectofCSH-macrophytesystemonphosphorousreleasefromsedimentandphosphoroustransformationinsedimentwasalsostudied.ItisrevealedthatthephosphorousremovalabilityofCSHisextremelyhigh,whichcouldarrive194.11mg/gforeachunit.Italsocanpreventphosphorousreleasingfromthesediment.Instaticstates,thephosphorousreleasingamountofthegroupwhich100gCSHwasaddedwasonly1/10ofthegroupwithoutCSHafter50days.ThereasonisthatFe-PandAl-PwhichiseasytoreleasecanbetransformedtoCa-PandEx-PwithCSH,andmainlyintheexistenceofstableCa-P.Whenadding50mgCSH,theproportionofAl-PandFe-Pintotalphosphorousofthesedimentwasdecreasedby26%,whilethatofCa-Pwasincreasedby24%.StudyalsoshowedthatthedosageofCSHcanpromoteMyriophyllumSpicarumabsorbingEx-Pfromthesediment,phosphoroustransferringfromsedimenttoplantandthegrowthoftheplant.Thephosphorousamounti