水泥结合氯离子能力测试方法与影响因素分析-test method and analysis of influencing factors of cements chloride binding capacity.docxVIP

ABSTRACTChlorideisanimportantfactortocausecorrosionofrebarinconcrete.Chlorideioninconcreteexistascombinationorfreestate.Itisgenerallyrecognizedthatonlythefreechloridesareresponsiblefordepassivatingthereinforcementsteel.Thatis,themoreboundchlorideions,thesmallercorrosioneffectofchlorideiononthesteel.Thecapacityofcementbindingchlorideisaffectedbymanyfactors,suchasthetypeofcement,auxiliarycementitiousmaterials,carbonation,chloride,sulphateetc,especiallysulphate.Theexistingformsandtypesofsulphateincementarecomplex,therefore,thispaperfocusesontheeffectsofsevenkindsofsulphate:sodiumsulfate(N),potassiumsulphate(K),sodiumpotassiumsulphate(KN),potassiumcalciumsulphate(KC),dihydrategypsum(CH)andanhydrite(C)existingincementadditionalmagnesiumsulphate(M),expoundingrespectivelytheinfluenceofthemonthecapacityofcementbindingchlorideion.Studyingonthecapacityofcementbindingchlorideion,themostimportantthingisdeterminingchlorideionconcentrationaccurately,sothetestmethodisthekey.ComparedwithMohrmethod,ammoniumthiocyanatemethodismoresuitable.Duetothecomplexityofthecementsystem,ammoniumthiocyanatemethodisoptimizedtoguaranteetheaccuracyandprecisionoftheresults.Theconcentrationoftotalchlorideionandfreechlorideionisdeterminedincementadmixeddifferenttypesanddosagesofsulphatebyoptimizedammoniumthiocyanatemethod.Theproportionofcombiningchlorideionsinthetotalchlorideionsrepresentsthecapacityofcementbindingchlorideion,thatis,themoretheproportion,thegreaterthecapacity.Thispaperalsoexpoundthedifferencesofthecementperformancebetweenthecementcombiningchlorideionandthecementbothaddedsulfateandcombiningchlorideion.Thecementperformanceisanalysedbymicro-XRDandelectrochemicalimpedancespectroscopytechniques.TheresultsshowthattheaccuracyofammoniumthiocyanatemethodishigherthanMohrmethod,butammoniumthiocyanatemethodalsohavesomeshortages,suchasconsumingtoomuchtime,pooraccuracy.Soammoniumthiocyanatemethodisoptimizedtoguaranteetheaccuracyprecisionandsuitableconsumingtimebyadjustingexperimentprocedures、concentra