水热合成条件对锆钛酸铅粉体形貌影响的分析-influence of hydrothermal synthesis conditions on morphology of lead zirconate titanate powder.docxVIP

AbstractUsing(C4H9O)4Ti,ZrO(NO3)2,Pb(NO3)2,NH3·H2Oasrawmaterials,KOHasthemineralizer,PVA（10%）andPAAasthepolymer,single-phaseandtetragonalperovskitePb(Zr0.52Ti0.48)O3(PZT)powdersweresynthesizedbyhydrothermalmethodat200°C.EffectsofKOHconcentration,thepolymer,Pbexcessandhydrothermaltemperaturewereinvestigated.ThemorphologyandmicrostructureofthepowderswerecharacterizedbymeansofX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).TheconcentrationofthemineralizerhasagreatinfluenceonmorphologyofthePZTpowders.TheconcentrationofPb2+vacanciesincreasedwiththeincreaseofthealkalinity.ThiskindofdeficiencycouldbecompensatedbyaddingmorePbionsintherawmaterials,andmorePbionswereneededtoaddwithhigheralkalineconcentrationinthestartingsolution.ButexcessivecompensationofPbionswouldresultintheappearanceofthesecondphase.ThesinglecrystallinetetragonalpeorvskitePZTnanorodsornanowiresweresynthesizedbypolymerassistedhydrothermalreactionmethod.TheeffectofPVAandPAAonthesynthesisofPZTone-dimensionalnanostructurewasdiscussed.TheadditionofPVAcouldmodifythesurfaceofthegrains.Itpromotesthegrowthofthegrainorientation.Meanwhile,asthechemicalsofttemplatethepolycrystallinenanotubesweresynthesized.Intheprocessofformationone-dimensionalnanostructuresofPZTcrystal，Undertheactionofhydrogenbondorchemicalbond,thepolymerchainofthePVAandPAAadsorptiononthesurfaceofmicrocrystalline,whichreducedsurfaceenergyofthesurfaceandenhancedthedeferentialofsurfaceenergybetweenotherfacetsandthegrowingfacet,resultingofthePZTgrowalongthe[001]direction.ThenanowiresofthePZTweresynthesized.Keywords:PZT;hydrothermalsyntheses;KOHconcentration;PVA;Pb目录摘要..............................................................................................................I?????????........................................................................................................II1绪论1.1压电陶瓷.................................................................................................(1)1.2锆钛酸铅(PZT)压电材料概述................................