水相体系中cdseag及znsecu掺杂量子点的合成与表征-synthesis and characterization of cd seal and zn secu doped quantum dots in aqueous phase system.docxVIP

子点的光谱测试结果表明，与CdSe:Ag掺杂量点相似，Cu的掺入出现了新的掺杂发射峰，不仅抑制了ZnSe量子点的本征发射，同时也改善了ZnSe量子点的表面缺陷态使其缺陷发射消失。结合光学图谱及量子点的能级示意图分析，Cu掺杂在ZnSe半导体量子点带隙之间形成一个新的杂质能级，导带中受激发电子与价带空穴在杂质能级发生辐射性复合，造成Cu的掺杂发射。此外，我们探讨了回流时间及配比的对ZnSe:Cu掺杂量子点的荧光性能影响。在配比为Zn/Se=1.2:1时，荧光发射在回流时间为60min时达到最强。通过控制反应配比可以获得尺寸连续变化的ZnSe:Cu掺杂量子点，其荧光发射范围从463nm覆盖到了518nm，相应的量子产率最高可达27%。关键词：量子点，水相体系，CdSe，ZnSe，Ag掺杂，Cu掺杂，Stokes位移SynthesisandCharacterizationofCdSe:AgandZnSe:CuQuantumDotsinAqueousPhaseABSTRACTSemiconductorquantumdots(QDs)havetremendousprospectinthefieldofsolarcells,light-emittingdiodes,biomedical,duetotheirexcellentopticalandelectricalproperties,suchasabsorptionandemissionwavelengthtunable.Atpresent,mostoftheQDsaresynthesizedintheorganicphasewithhighlytoxicandexpensivesyntheticmaterial,andwhichrequireahighertemperature.Thesurfaceoftheobtainedquantumdotsisoftencappedwithhydrophobicorganicligandthatmustberemovedbyligandexchangewhiletheywereappliedinthefieldofbiomedicineorusedforfabricatingdevices.Asweknow,changingthesizeandcompositionofthequantumdotsisthebasicmeansforcontrollingtheirproperties.However,inordertobroadenthefluorescenceemissionrangeofQDs,itisdifficulttoachieveintheactualoperationbypreciselycontrollingofthecompositionorreducingtheparticlesize.WhiletheQDsareextremelysmall,theperformancewouldbedroppedrapidlythatresultingfromthedefectsofthestructureandsurface.Althoughitcanbeobtainedoverawiderangeofemissionwavelengthwithdifferentsizesofquantumdots,aseriousre-absorptionphenomenoncertainlyappearssincethequantumdotsarecombinedtogether,whichwilldirectlyleadtotheconversionefficiencyofthedevicedecreases.Inthisdissertation,wehaveobtainedtheresultsaslistedasfollowing:Firstly,CdSequantumdotscappedwithMPAweresimplysynthesizedviaaqueousphasereaction.WetookadvantageofasimpleandfeasibleelectrochemicalmethodtoprepareH2SeastheSesource.BoththerefluxheatingtimeandtheelectrolytictimeforpreparingH2Segaswerediscussed.Throughprolongingtherefluxheatingtime,theemissionwavelengthoftheobtainedCdSequantumdotswouldmovefrom456nmto502nm.Andbyadj