砷 镉在二氧化钛表面共吸附及其机理分析-co-adsorption of arsenic and cadmium on titanium dioxide surface and its mechanism analysis.docxVIP

3udyofCadmiumandArsenateCo-adrorptiononTi02sp配ialty:EnvironmentalEngineeringAuthor:HuShanInstructor:prof.Nie讪fai-qianprof.JingChuang-yongAbstractAnatase(As(V))andcadmium(Cd)arewidelyusedindustrialmaterialswithavarietyofapplications，includingpigments，cosmetics，ceramics，solarcells，andmetalsmeltinginrecentyears，leadingtothegreatlyincreaseofAs(V)andCdconcentrationsinnaturalwaters，whichisharmfultohumanheathy.Anumberoftraditionalheavymetalremovalmethods，forexample，precipitation，ionexchange，neutralization，andfilmfiltration，buttheyallhavetheshortcomingslikelowremoval，difficulttorecycle，expensive，andgenerateslotsofsluge.Adsorptionovercomestheseshortcomingsandbecomesawidelyusedheavymetalremovalmethod.AzeroslugeandAsremediationtechnolygyforacidicmetallurgicalindustrywastewaterwasdevelopedbyTi02adsorption.Theeffectofcadmium(Cd)andarsenate(As)co-adsorptiononthetitaniumdioxide(Ti02)surfacewasinvestigated.Multiplecomplirnentarytechniquesincludingbatchadsorptionexperimen邸，surface-enhancedRamanscatteringspectroscopy，Zetapotentialmeasurements，Fouriertransforminfraredspectroscopy，andcharge-distributionmultisitecomplexationmodelwereusedforthequantitativeanalysisandthedetelminationofthestructureofsurfacecomplexes.Theresultsareasfollows.TheTi02adsorptionresultsshowthatexistofAs(V)willpromoteCdremovalTheCdremovalinctras巳dfrom334.0mg/gTi02and661.9mglgTi02to458.2mg/gTi02and848.7mg/gTi02andpH5andpH7.TheCdremovalincreaseastheincreaseofAs(V)concentrationatpH3-8.Atthesametime，theexistofCdwillpromoteAs(V)removalatpH3-10.TheadsorptionkineticsshowthatbothsingleAsandCdadsorptiononTi02followedpseudosecond-orderkineticsandreachedequilibriumwithin15and40minWhenCdandAsco-adsorbedonTi02，theadsorptionkineticsfollowedpseudofirsl-orderandrequiredmuchlongertimetoreachequilibriumTheadsorplionmechanismstudyshowthatAs(V)andCdwillnotformcomplexationinsolulionatlowAsconcenh刽ions(As=10mg.V1，Cd=75mg.Lη，bothAsandCdformedbidentatebinuclearinner-spheresurfacecomplexesonTi02surfaces;whenathigerAs(V)concentl划ion(As150m