四氮杂大环铜配合物催化的b-z化学振荡体系测定茜素红s和维生素类物质-determination of alizarin red s and vitamins by b - z chemical oscillation system catalyzed by tetraaza macrocyclic copper complex.docx

AbstractChemicaloscillationisanonlinearnon-equilibriumphenomenon,whichisfoundinthenaturalsciences.Someoscillationphenomenahadbeenobservedinlifesystem,suchasheartbeat,respirationandmetabolism.Thespecialbehaviorsofoscillatingchemicalreaction,especiallytetraazamacrocyclecomplexescatalyzedoscillatingchemicalreactions,havebecomeofgreatinterestinmanyscienceworkersrecently.Thesetetraazamacrocycliccomplexeshaveasimilarstructuretosomeenzymesoflifesystem.Therefore,ithasfar-reachingsignificancetostudiesofoscillatingreactionscatalyzedbythesecomplexesthatwillhelpustosimulateoscillationphenomenainplantsandanimals.AnovelB-Zoscillatingsysteminvolvesamacrocycliccopper(Ⅱ)complex[CuL](ClO4)2ascatalystandmalicacidasthesubstrate,wasappliedtodeterminecalciumpantothenate,inositolandVB6.TheligandLinthecomplexis5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dine.Thedissertationcontainsthefollowingworks:TheSummaryofchemicaloscillatingreactionThischapterreviewssomeresearchofchemicaloscillation.Itintroducesthebasicconditionsforchemicaloscillatingreactionanddescribesseveralusualoscillatingchemicalreactions.ThemechanismsofclassicalandnovelB-Zoscillatingreactionweredescribedindetails.Theapplicationofoscillatingchemicalreactionsintheanalyticalchemistryandthedevelopmentprospectsarealsoreviewed.Chemicalsynthesisofmacrocycliccomplex[CuL](ClO4)2andthedeterminationofAlizarinRedSFirstly,Thetetraazamacrocycliccomplex(catalyst,[CuL](ClO4)2)wassynthesizedaccordingtoliteratureandwasidentifiedbyI.R.spectrumandelementalanalyses.Then,establishthestablenovelB-Zoscillatingsystem,whichinvolvesamacrocycliccopper(Ⅱ)complex[CuL](ClO4)2ascatalystandmalicacidasthesubstrate,todetermineAlizarinRedS.SeveralrepeatedexperimentsindicatedthatthereisapolynomialrelationshipbetweenthechangesoftheoscillatingamplitudeandthelogarithmoftheAlizarinRedSconcentrationovertherange1.5×10-7to1×10-3M.Theforeignionsinterferenceswerealsostudied.Besides,cyclicvoltammetry(CV)isemployedtostudythemechanism.Aproperexplanationbased