水热法制备纳米三氧化钨及其气敏性能分析-preparation of nano-sized tungsten trioxide by hydrothermal method and analysis of its gas sensitivity.docxVIP

ABSTRACTTungstentrioxide(WO3)isatypicaln-typesemiconductorfunctionalmaterials,itisalsooneofthecommonmetaloxidesemiconductor(MOS).Inthepastfewdecades,WO3hasattractedtheaffectionofmanyresearchersduetoitsnumerouspotentialapplicationsingassensors,electrochromism,chemicalcatalysisandelectrochemistry,etc.Thedesignandrationalsynthesisofmetaloxidesemiconductorswithtailoredcharacteristics(morphology,crystalphase,components,crystallinity,etc)haveattractedincreasingattentionbecausetheylargelydeterminethevariouspropertiesofthematerials.Theintroductionofmodernnanometermaterialscienceandtechnologyeithercanenhancesomeperformanceofmaterialstoacertainextentormakesitshowsomeunexpectedproperties.Thehydrothermalsolutionmethodandwaterbathmethod,whicharebelongtosolutionmethod,havetheadvantagesofsimpleeconomy,lowenergyconsumption,andmakingthenanomaterialhighcrystallinityandpurity,etc.However,thechangingPHvalue,hydrothermaltemperatureandtime,kindsandconcentrationsofauxiliaryagentinthesolutionhaveimportantinfluenceonthesize,shape,structureandcrystallinestructureofWO3.Atthesametime,forthesamekindofcrystalphase,theinfluenceofdifferentsizeandmorphologyofWO3onpropertiesofitsgassensitivityremainstobefurtherimproved.Therefore,hydrothermalpreparationofnanometerWO3,growthmechanismandgassensitivepropertiesresearcheshaveextremelyimportantsignificanceontheoryandpractice.Maincontentofthisarticleisasfollows:Firstly,westudiedtheinfluenceofdifferentsizeandmorphologyofWO3ontheperformanceofgas-sensingproperties.Wepreparedcubic-likeparticlemonoclinicphasenanometerWO3,plate-likeandlayeredflower-likeWO3·H2Obyhydrothermalmethodandwaterbathmethod,respectively,wheresodiumtungstatewasusingasrawmaterials,CTABandoxalateasauxiliaryadditives.TheWO3·H2OtransformedtomonoclinicWO3andkeeptheoriginalplatesandflower-likestructuresaftersinteringprocessing.ThebestworkingtemperatureofthedifferentsizeandmorphologyofWO3is300℃andflower-likestructureshowedthehighestsensitivity.Theresultsshowedthatthemorphologyandsizemonoclinicphas