湿污泥热解影响因素与产氢途径的分析-analysis of factors affecting pyrolysis of wet sludge and ways of hydrogen production.docxVIP

反应。采用Excel拟合建立湿污泥热解过程产物变化的经验方程，预测继续扩大温度范围，气体产率会继续上升，H2、CO总含量和H2/CO值也会有相应提高。关键词：湿污泥热解干污泥气化影响因素产氢途径AbstractWiththeprogressofcitymodernization,municipalwastewatersewagesludgewerealsoshowedincreasingtrend,howtoeffectivetreatmentanddisposalofsewagesludgearestilltoberesolved.Thetraditionalsludgedisposalmethodscannotmeetthesocialdemand,pyrolysisgettheattentionofresearchworkerswithitsadvantagewitchmaximizetheenergyrecyclinginminimalhazardby-product.Wetsludgemoisturecanpromotehigh-qualitycombustiblegasgenerated,fromtheeconomicperspective,thispapersumminguptheexperienceandcontinuetoexplorethewetsludgepyrolysishydrogenoptimalconditions,theadvantageofwetsludgepyrolysisdirectly,theformationandthetendencyofH2,themaincontentsandconclusionsareasfollows:Theexperimentsystemwascomposedoftubetypehightemperatureelectricheatingfurnace,steamgeneratorandotheraccessories,summeduptheinfluenceregularpatternofpyrolysisproductsandgaseouscomponentsofsinglebatchfeedingamount,reactiontimeandthewaytoheating-up.Theexperimentalresultsshowthat,whenfinaltempretureis1000℃,asinglebatchoffeedratefor250gwetsludgecangethighqualityhydrogenrichgasinashortperiodoftimeforthediviceofthisexperiment;Reactionhasbeenbasicallycompletedin45min,themajorityofhydrogenrichgashasgenerate.Usetheheatingmodewitchthefirstsettingtemperatureistheendtemperature,improvestheheatingrate,moreintermediateproducttakepartinhightemperaturecatalyticreactionandthetwocleavagereaction,leadingtoCH4andCO2contentwithlesserdegreesofreduction,whileH2andCOcontenthasbeensubstantialgrowth.Underthesameconditions,wetsludgepyrolysiscangetmoreH2andCOhighqualitygasthandriedsludgegasification.Analysesthethree-phaseproductcompositionsandelementscontent,investigatingthewayhydrogenproduct,andpredictthehydrogenproducttrend.Afterdryingtherawsludgemaycontainsubstances:alcohol,amine,ester,ether,alkenes,olefins,acid,aliphatichydrocarbonsandaromaticcompounds,aftermorethan600℃ofpyrolysisreaction,thecomponentsarereducedaccordingly;Thecollectedtarwereconsistedofthear