十一烯醇丙烯共聚物的制备及其对聚丙烯亲水性的改性分析-preparation of undecenol propylene copolymer and analysis of its hydrophilic modification on polypropylene.docxVIP

功能性聚丙烯时，体系的机械性能严重下降，发生脆性断裂。关键词：共聚，共混，亲水性，聚丙烯PREPARATIONOF10-UNDECEN-1-OL/PROPYLENECOPOLYMERANDHYDROPHILICMODIFICATIONRESEARCHOFPOLYPROPYLENEBLENDSABSTRACTPPisusedinawidevarietyofapplicationsduetoitsexcellentpropertiessuchaslowcost,highmechanicalstrength,flexibility,chemicalstabilityandprocessibility.However,theinertnatureleadstoanincompatibilitywithotherpolymersorinorganicfillerstoaffectfurtherapplicationofPP.Inthispaper,weinvestigatedmodificationapproachofPPbymeansofcopolymerizationandblending.Copolymerizationofpropyleneand10-undecen-1-olwasconductedwithfluorenylamidodimethyltitaniumcomplexesactivatedbymodifiedmethyaluminoxane(MMAO)and2,6-isopropyl-phenol(BHT)ascatalyst.Thecatalystsystemshowedveryhighactivity(810-47040kg·mol-1·h-1)toproducehighmolecularweightrandomcopolymerswithMnvalueof150000-450000,andthecomonoercontentwasincreasedwiththeincreaseoftheamountofcomonomer.Theseresultsindicatethathydroxylfunctionalizedpolypropylene(PP-OH)weresynthesizedwithhighmolecularweightandcontrollablehydroxylcontentviacoordinationpolymerization.PP/PP-OHblendswerepreparedbymeltblendingisotacticPPandPP-OHwithvariousweightratios.Theresultsofcontactangle,ATR-FTIR,DSC,TGAandtensiletestinganalysistestifiedthatthewatercontactangleofPP/PP-OHblendwasdecreasedfrom117°to98°withincreasingtheamountofPP-OH,thehydrogenbondwasobservedintheblendingsystem,PP/PP-OHblendsshowedlowermeltingpointsthanisotacticPP,whilethedecompositiontemperaturesofblendswerealittlehigherthanisotacticPP.WhenaddedisotacticfunctionalpolypropylenetoPP,itwashelpfultoimprovemechanicalpropertiesofblends,andthesystemsmaintainedtheformofductilefracture.However,whenaddedrandomfunctionalpolypropylene,therewasaseriousdeclineinthemechanicalpropertiesofthesystems,andtheblendsoccurredbrittlefractures.WeiLijing(MaterialScienceandEngineering)SupervisedbyprofessorCaiZhengguoKEYWORDS：copolymerization,blend,hydrophilic,polypropylene目录摘要.......................................................................................................