生物塑料聚乳酸pla及聚3-羟基-co-4-羟基丁酸酯p34hb性能改进研究-study on improvement of properties of pla and p34hb of poly ( 3 - hydroxy - co - 4 - hydroxybutyrate ).docx

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生物塑料聚乳酸pla及聚3-羟基-co-4-羟基丁酸酯p34hb性能改进研究-study on improvement of properties of pla and p34hb of poly ( 3 - hydroxy - co - 4 - hydroxybutyrate ).docx

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生物塑料聚乳酸pla及聚3-羟基-co-4-羟基丁酸酯p34hb性能改进研究-study on improvement of properties of pla and p34hb of poly ( 3 - hydroxy - co - 4 - hydroxybutyrate )

AbstractPoly(lactide)PLAisakindofthermoplasticpolymerwithhightensilestrengthandmoulus.thepoorimpactresistanceandlatercrystallizationlimititsdevelopmentandpracticalapplication,Weblendthebiodegradablepoly(3-hydroxybutyrate-co-4-hydroxybutyrate)(P3/4HB)withPLAtoovercomethesedefectsofPLA.ThephysicalpropertyofP3/4HBisfromsemi-crystallizationplastics(e.g.5%4HBcontent)toamorphouselastomers(e.g.30%4HBcontent)dependingonthe4-hydroxy-butyrate(4HB)content.Inthiswork,threekindsofP3/4HB（P(3HB-co-10%-4HB)、P(3HB-co-20%-4HB)、P(3HB-co-32.4%-4HB)）werechosen,PLAwasblendedwithP3/4HBwithvarious4HBmolarcontentsbymeltmixing,WestudiedtheeffectsofP3/4HBwithvarious4HBcontentsandP3/4HBcontentsonthecrystallizationbehaviorsandmechanicalpropertiesofPLA.ExperimentalresultsindicatedthatTheP(3HB-co-32.4%-4HB)coulddecreasethecrystallizationhalftimeofPLAfrom26.53minto5.92minwhenisothermalcrystallizationtemperaturewas95℃.forblendsofPLA/P(3HB-co-20%-4HB),whenP(3HB-co-20%-4HB)was20wt%,excellentcomprehensivepropertieswereobtainedwithtensilestrengthof44.21Mpa，Young’smodulusof2.85Gpa，elongationatbreakof82.78%andimpactstrengthof17.02KJ/m2.Inaddition,Mixingorganicorinorganicfillerswithlowercostsuchas:calciumcarbonate、plantfiber、talc、Wollastonite、starch,etccouldcoordinatethestrengthandtoughnessofPLAandreducetheusingcostofPLAandP3/4HBunderthepremiseofcompletedegradation.Wechoosetalcwithlamellarstructure、wollastonitewithfibroustextureandP3/4HBtostrengthandtoughthePLA,Theresultsindicatedthattalctreatedbycouplingagentcouldimprovethetensilestrengthandimpactstrengthofthecompositesgreatly,buttheelongationatbreakdecreased.However,theelongationatbreakofcompositesfilledwithwollastonitetreatedbystearicacidcouldbekeptinhighstate.Thusaddingthesedifferentfillerssimultaneouslycouldcombinetheadvantagesoftalcandwollastonitetoacquirethecompositeshavinggoodcomprehensiveproperties.Forexample,weblendtalcandwollastoniteat3:1,whenthefillercontentwas20wt%,thetensilestrengthwas41.88Mpa,elasticmoduluswas3.45Gpa,impactstrengthwas39.03K