石墨烯纳米二氧化钛复合材料的制备及其光催化降解2,4-二氯苯酚的研究-preparation of graphene nano-titanium dioxide composite and its photocatalytic degradation of 2,4 - dichlorophenol.docxVIP

AbstractTiO2isusedasphotocatalystinthisarticle.Duringtheprocessofphotocatalysis,thevalueofpHwaschangedinsolution.Thereasonofthischangeistheformationoforganicacidswhichhavesmallmolecularweightinthereactionsystem.ThephotocatalyticreactionrateisextremelysensitivetothechangeofpHvalue.Therefore，thepHvalueofsolutionmustbestabletogetaccurateresults.BycarryingoutthephotocatalysisinNa2CO3-NaHCO3buffersystem,thisproblemcanberesolvedperfectly.Onthisbasis,theprocessofphotocatalysisontheweaklyalkalineenvironmen（tpH=9）wasresearched.Andexperimentalresultshaveshownthattherateofphotocatalyticdegradationinalkalineenvironmentishigherthanwitchinacidicandneutralconditions.DCPwastewaterthatcamefromactualproductiongenerallyhaveahighconcentrationofNaCl.ThepresenceofNaClwillsignificantlyreducethecatalyticactivityoftitaniumdioxide.IthasbeensuggestedthatthecombinationofTiO2withgraphenecouldreducethelevelofelectron-holerecombination.Inordertoimprovetheefficiencyofphotocatalysis,TiO2andgraphenethatpreparedbythemethodofHummersandTiO2werecombined.Byhydrothermalmethod,graphene-TiO2compositephotocatalystwithdifferentweightratiosofgraphenetoTiO2(0,0.01,0.02,0.05,0.10respectively)wasprepared.Experimentsaboutthephotocatalyticperformanceofgraphene-TiO2compositephotocatalystshowthatcatalyticactivityofthecompositephotocatalystcomparedtopuretitaniumwasimprovedsignificantlyinalkalinereactionsystemwithhighconcentrationofsodiumchloride((pH=9,Na2CO3-NaHCO3buffersystem,20%NaCl).Andthecatalyticactivityofcompositephotocatalystwasincreasedwiththepaceoftheincreaseofgrapheneconcentrationwhengraphenelevelislessthan5%.ThereasonofthisphenomenonisthattheBETofgrapheneincreasedsothatDCPwouldbeadsorbedonthesurfaceofphotocatalystrapidlyandtheseparationofelectron-holepairwasveryefficient.Whenthegraphitecontentismorethan5%,graphenewouldsuppresstheabsorptionoflightandthecontentoftitaniumdioxideincompositephotocatalystwouldbereducedaccordingly.Therefore,allofthesefactorsrepressedthecatalyticactivityofcompositephotocatalyst.Key