石棉尾矿制备轻质氧化镁的清洁生产工艺分析-analysis of clean production process for preparing light magnesium oxide from asbestos tailings.docxVIP

consumptionofcleanerproductionmaterial,wedidcomparativestudyofconditions,suchasoreparticlesize,acidtypeandamount,liquidtosolidratio,leachingtimeandadditionofcosolvent.Weconsideredtheleachingrateofmagnesiumasindicator,determinedtheoptimalconditions:80meshore,liquidtosolidratioof4:1premised,after1hourimmersedin120%sulfuricacidand1%cosolventacidenvironment,magnesiumleachingratefromoreisupto98.76%,morefeasiblethanpreviousstudiesoftheconditionsResearchanddevelopmentaboutmulti-effectseparationagentforimpurities.Afterleaching,thecrudesulfatesolutioncontainsironimpurities,ifdonotremoveironimpurity,itwillcausephenomenonofironoxidered.asIronprecipitator,AmmoniaandSodiumhydroxidearenotideal,andtheywillpolluteenvironmentandcorrodeequipmentofoperation.Tosolvethisproblem,,wedevelopednewandmoreeffectivereagentofseparatingimpurityfromtheperspectiveofcleanproduction.Wetoketherateofironremovalasreference,andcomparedthenewwiththetwopreviousreagents.theresultshowsthattheseparationrateofmulti-effectdoseisupto99.94%,withoutphenomenonofironoxidered,thisnewreagentachievedgoalofcleanerproduction.Therefore,multi-effectseparationreagentwasdeterminedasthebestprecipitant,andoptimalpHvalueofmulti-effectseparationreagentwasbetween5.5and6.5.SelectionconditionsforpreparationoflightMgO.Ourexperimentchoosedpowder,slurryandclarifiedliquidofsodiumcarbonateasstudyobjecttofindoutoptimalprecipitationmodeandthebestagingtime.Whenprecipitatewasformedthendried,temperatureandtimeofcalcinationwereofoptimalchoice.thesolutionbyaddingNa2CO3clarifiedliquidcompletelyreacted,afterimmediatefiltrationwithoutaging,theproductofhighestpuritywasobtainedin850℃calcinationin2.5h.WashingwithhotwateristhekeyproceduretoqualityofMgO.Aftertherecoveryofby-products,thereisnointerferenceinwasteliquid,thatcanbeusedasindustrialwaterbacktomotherliquor,thusthisprocessreflectedthecharacteristicsoclosedlooptechnologyandcleanproductionintheeradicationsecondarypollution,reducedloadofendprocessingMeasurementandAnalysisofqualityofMgOproducttoe