石英和锆英石复合镁钙系材料的制备及性能分析-preparation and performance analysis of magnesium-calcium composite materials of shi ying and zircon.docxVIP

摘要3）引入锆英石可以大幅度提高试样的抗水化性能，对于不同MgO含量的试样，最佳的添加量也不同。4）提高烧结温度对试样的各项性能的优化非常明显，可以促使MgO晶粒明显长大；减少CaO晶粒内部气孔。关键词：镁钙系耐火材料烧结性能致密性抗水化外加剂VAbstractRefractorymaterialneedhaveacertainsizestability,hightemperatureresistantperformanceandcorrosionresistance.Hightemperatureequipmentgenerallyneedsrefractorymaterialaslining,sotherefractorymaterialisanindispensablepartofhightemperatureindustrial.Alongwiththedevelopmentofmetallurgicaltechnology,thedemandforpuresteelandhigh-gradesteel,thecontinuouscastingratioincreasesgradually.thetechnologyofrefiningoutsidethefurnaceisdeveloping.Theladleofsmeltingcleansteelneedrefinesecondarymoltensteel,whenitwaslayingupanddelivering,whichforcetherefractorymaterialchange,improveanddevelopforhigh-graderefractorymaterials.Calciummagnesiumseriesrefractoryspowerfulsuperiorityisattendedgraduallybypeople,whichincludehightemperatureresistance,goodresistancetoslagpenetrationability,andalsocanpurifyliquidsteel.Inmanyoxiderefractorymaterials,CaOnotonlyhashightemperatureresistance,butalsopuryliquidsteel.SomagnesiumcalciumseriesrefractoryishonouredasoneofthefourmaindevelopdirectionofrefractorymaterialsinChinainthe21stcentury.Calciummagnesiumseriesrefractoryhasverymanyexcellentproperties,italsoexistsomeproblems,oneofthemostimportantproblemisthefreeCaOhydration.Inordertoenhancethehydrationresistanceofmagnesiumcalciumseriesrefractory,commonmethodsaredividedintothefollowingkinds:thefirstissurfaceprocessing;thesecondisintroductionofadditives;thethirdischangethesinteringtechnology.Sofar,thestudyfoundthattheadditiveswhichisgoodforcalciummagnesiumseriesrefractoryhydrationresistanceinclude:BaO,SrO,Al2O3,Fe2O3,B2O3,Y2O3,SiO2,Cr2O3,TiO2,ZrO2,CaF2,rareearthoxidesanditscomposites,etc.Themethodofimprovingthesinteringtechnologygenerallyincludestwostepsinteringmethodandhightemperaturesintering.Thissubjectuseslightburneddolomite,lightburnedmagnesiteasmainrawVImaterials,quartzandzirconasadditives.Wewillstudythecompactness,hydrationresistance,microstructureandphasecompositionofsamples,byu