石油焦和生物质共气化动力学研究-kinetics of co-gasification of petroleum coke and biomass.docx

approximationwereusedforSCBcharsgasification.Themainresultscanbecategorisedintoseveralparts:Firstly,theCO2gasificationofthePCtookplaceinonlyonestage(chargasificationstage)attemperatureshigherthan800°Cand700oCfornon-catalyticandcatalyticgasification,respectively.DuringsteamgasificationwithH2Oconcentrationof25and50%PCispresentedintwostages,whichwerepyrolysisstageatlowerthan500°Candchargasificationstageathigherthan700°C.IftheH2Oconcentrationwas75%,thePCispresentedinonlychargasificationstage.Ontheotherhand,thegasificationofSCBcharstookplacealmostcompletelyinonestageprocessattemperaturehigherthan600°C.ThemainreleasedgasesareCOandCO2obtainedathighertemperature(700°C),andCH4,HCOOH,C6H5OHandCH3COOHobtainedatlowertemperature(500°C).Secondly,theadditionof7wt%FeCl3toPCleadstoimprovethereactivityofPCfrom1.39%/minupto2.19%/minanddecreasetheactivationenergyfrom218.12kJ/molto170.32kJ/mol.Ontheotherhand,theaddition5wt%FeCl3forchargasificationofSCBandblendleadstoimprovetheirreactivitiesfrom1.70%/minto3.45%/minandfrom1.25%/minto1.63%/min,anddecreasetheiractivationenergiesfrom134.87kJ/molto120.42kJ/molandfrom138.70kJ/molto114.90kJ/mol,respectively.Thirdly,signi?cantsynergisticeffectsexistedinbothreactionstagesoftheblendgasification,especiallyforthegasificationwiththePCcontenthigherthan75%.Aswellas,theeffectsismoresignificantforthecatalyticgasification.Fourthly,aspyrolysistemperatureincreased,theatomicratiosofH/CandO/Cdecreasedcontinuouslyfrom1.55and0.74inpureSCBto0.29and0.22forthecharpreparedat900°C.TheSCBcharreactivityisdirectlyproportionaltogasificationheatingrate.Thehydroxyl,aliphaticC–H,carbonylandole?nicC=Cgroupswerelostatpyrolysistemperatureshigherthan800°C.Fifthly,theH2Oco-gasificationbehaviourandkineticparametersweresignificantlyaffectedbyincreasingtheH2Oconcentration,PCcontentandFeCl3loading.Theactivationenergyincreasesby36.44%whentheH2Oconcentrationincreasesfrom25to75%,whichareachievedbythemodelR2.Similarly,theresultsoffuelblendeffectsshowthattheactivationenergyincreasesby77