石墨粉电镀法镀覆铜 锌 银工艺分析-analysis of copper-clad zinc-silver plating process with graphite powder electroplating method.docxVIP

石墨粉电镀法镀覆铜、锌、银、工艺研究onesmadebytraditionalmethods.Theresultsshowthatzinc-platedgraphitecompositehaslowerresistivity,higherdensity,hardnessandbendingstrengthwhichindicatesthatitisakindofnewmaterialwithexcellentproperties.TheeffectsonsilvercontentofAgNO3concentration,theamountofgraphitepowdersandcathodeefficiencywereanalyzedindetail.Theresultsshowthatbyusingsilveranodeaspositivepole,afineandclosesilverlayerwaselectroplatedongraphitepowderswhichwerepretreated.Thesilvercontentoftheproductcouldreach70wt%undersuchparameters:12g/LAgNO3,6g/Lpretreatedgraphitepowders,28g/Lsuccinimide,0.2～0.5A/dm2currentdensityrangeand8.5～10.0pHvaluerange.Themetalparticlesdispersivelydistributedinthemetal-platedgraphitecompositesandformthree-dimensionalnetworkwhichreducestheresistivityofthecomposites.Thebondingstrengthofmetalisstrongerthanthestrengthbetweenmetalandgraphitewhichincreasesthehardnessandbendingstrengthofthecomposites.KeyWords:Graphitepowders;Electroplatingtechnology;Electroplated-metalcontent;CompositeV插图索引图1.1电镀装置示意图…………………………………………………………….…2图1.2复合电镀电沉积三阶段示意图5图1.3两步沉积历程简图6图1.4MTM模型的5个步骤6图1.5并联吸附过程图7图1.6液滴的接触角15图1.7表面活性剂结构16图2.1电镀装置简图25图2.2石墨粉预处理流程图26图2.3电镀工艺流程26图2.4镀铜石墨粉850℃灼烧后残留物的X射线衍射图29图2.5镀锌石墨粉850℃灼烧后残留物的X射线衍射图30图2.6镀银石墨粉850℃烧后剩余物质的X射线衍射图31图3.1搅拌间隔时间对镀铜石墨粉含铜量的影响33图3.2浓硫酸加入量对镀铜石墨粉含铜量的影响34图3.3石墨粉加入量对镀铜石墨粉含铜量的影响35图3.4镀前石墨粉的粒度分布曲线37图3.5石墨粉镀铜后的粒度分布曲线………………………………………...……37图3.6预处理石墨粉的扫描电镜照片…………………………………………...…38图3.7镀铜石墨粉扫描电镜照片………………………………………………...…38图3.8镀铜石墨粉复合材料扫描电镜照片………………………………...………39图4.1搅拌间隔时间对镀锌石墨粉含锌量的影响……………………………...…41图4.2ZnO浓度对镀锌石墨粉含锌量的影响………………………………………42图4.3石墨粉加入量对镀锌石墨粉含锌量的影响………………………………...43图4.4NaOH浓度对镀锌石墨粉含锌量的影响………………………………….…43图4.5施镀时间对镀层镀锌率的影响…………………………………………...…44图4.6镀锌石墨粉与氧化锌的X射线衍射图……………………………………...45图4.7石墨粉镀锌后的粒度分布图……………………………………...…………46图4.8镀锌石墨粉扫描电镜照片………………………………………….………..47图4.9锌粉与石墨粉机械混合制得的石墨/锌复合材料扫描电镜照片….………48图4.10镀锌石墨粉制得的石墨/锌复合材料扫描电镜照片…………………...…49图5.1镀液AgNO3浓度对含银量的影响…………………………………….……52图5.2石墨粉浓度对镀银石墨粉含银量的影响………………………...…………53图5.3络合剂加入量对镀银石墨粉含银量的影响……………………...…………54