由金属烯烃polyoligomerizations precatalysts轴承不：（Olefin polyoligomerizations by metal precatalysts bearing non–heterocyclic N–donor ligands）.pdfVIP

Applied Catalysis A: General 535 (2017) 32–60 Contents lists available at ScienceDirect Applied Catalysis A: General j o u r n a l h o m e p ag e: w w w. elsev /locate/apc ata Olefin poly/oligomerizations by metal precatalysts bearing non–heterocyclic N–donor ligands Srinivasa Budagumpi a,b,∗ , Rangappa S. Keri a , Andrea Biffis b , Siddappa A. Patil a a Centrefor Nano and Material Sciences, Jain University,Jain Global Campus, Kanakapura, Ramanagaram, Bangalore 562112, India b Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, 35131, Padova, Italy a r t i c l e i n f o a b s t r a c t Article history: The use of transition metal complexes of non–heterocyclic N–donor ligands as olefin oligo/polymerization Received 16 November 2016 precatalysts is reviewed. These metal complexes with definite steric and electronic variations offer high Received in revised form 27 January 2017 catalytic activity resulting in the desired microstructure of the polymer products currently attracting sig- Accepted 2 February 2017 nificant attention by the catalysis community. This review primarily discusses the fundamental principles Available online 3 February 2017 in the design of mononuclear, homodinuclear, heterodinuclear, homomultinuclear and heteromultinu- clear transition metal complexes having non–heterocyclic N–donor ligands and their reactivity