温度的影响的活动和稳定性热水地准备IrOx nanocatalyst层的氧发生反应：（Effect of temperature on the activities and stabilities of hydrothermally prepared IrOx nanocatalyst layers for the oxygen evolution reaction）.pdfVIP

Applied Catalysis B: Environmental 218 (2017) 287–297 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j o u r na l h o m e p ag e: w w w. elsev /locate/apc atb Effect of temperature on the activities and stabilities of hydrothermally prepared IrOx nanocatalyst layers for the oxygen evolution reaction Gabriel C. da Silva, Nickson Perini, Edson A. Ticianelli ∗ Instituto de Química de São Carlos, USP, C.P 780, São Carlos, SP 13560-970, Brazil a r t i c l e i n f o a b s t r a c t Article history: Iridium oxide nanoparticles are prepared via a hydrothermal method, treated at different calcination Received 30 November 2016 temperatures, and their activities and stabilities for the oxygen evolution reaction (OER) evaluated. Received in revised form 13 June 2017 The catalysts are physicochemically characterized using several techniques including X-ray diffraction, Accepted 16 June 2017 energy dispersive X-ray spectroscopy, transmission electron microscopy, X-ray photoelectron spec- Available online 19 June 2017 troscopy, and X-ray absorption spectroscopy. Voltammetric profiles obtained for the catalysts calcined up to 300 ◦ C are similar to that of electrochemically prepared hydrous iridium oxide, while the CV profiles are Keywords: characteristic of thermally prepared iridium oxide after calcination at higher temperatures. Performance Iridium