生物可降解ca-p陶瓷颗粒增强镁基复合材料分析-analysis of biodegradable ca - p ceramic particle reinforced magnesium matrix composites.docx

而且 HA 颗粒的团簇尺寸也随着变形道次的增加而减少，复合材料的显微组织更 加均匀，ECAE 的挤压过程可以使试样的 ED 面部分上与 Mg 晶格的基面平行， 由于镁晶格的基面具有更高的结合能，因此 1HA/Mg-Zn-Ca 复合材料的 ED 面具 有更好的耐腐蚀性。 关键词：镁基复合材料，晶粒细化，热模拟，等通道转角挤压，显微组织， 耐蚀性  Abstract Magnesium and its alloy have potential to be bone repair devices, stents, hemostatic clip and other biodegradable implant materials due to its light weight, appropriate mechanical property, biological safety and degradable property. However, magnesium and its alloy exhibited a high corrosion rate in the physiological environment containing Cl- , thus lead to the rapid loss of mechanical strength, quickly increase of pH value and the mass release of hydrogen.therefore, above problems are the main obstacles of magnesium alloy application in clinical. To slove this key problem , Ca-P bio-ceramic particles were used to be refinement in magnesium matrix composite in this paper, which can refine grain size, enhance corrosion resistance and mechanical properties. In this paper, pure Mg with different grain size was prepared by controlling the cooling rate and Mg-30%Ca alloys were prepared by the vacuum smelting to research effect of grain size and β-phase on corrosion behavior. The high shear melting technology was used for preparing 1HA/Mg-3Zn-0.2Ca composites and 1β-TCP/Mg-3Zn-0.2Ca composites which were characterized by optical microscope (OM), scanning electron microscope(SEM), transmission electron microscope(TEM) and X-ray diffraction analysis(XRD). The corrosion mechanism of the composites were studied by electrochemical test. And the influence of reinforcement addition on the hot deformation behavior of Mg-Zn-Zr alloys was studied by the hot compression experiment. The as-cast composites were deformed by equal channel angle extrusion(ECAE), and the effect of ECAE to microstructure, texture, and electrochemical behavior was researched. The main conclusions are as follows: Grain refinement can increase the corrosion sensibility of magnesium matrix materials.The magnesium matrix materia