疏水表面纳米气泡特性及固液边界滑移长度关系分析-characteristics of nano-bubbles on hydrophobic surface and analysis of the relationship between solid-liquid boundary slip length.docxVIP

AbstractThenanobubbleswerefirstlyproposedtoexplainthehydrophobiclong-rangeforcemechanism.Withthecontinuousprogressofthemicro-nano-measurementtechniquesandmeasuringinstruments,notonlyintheory,nanobubbleswerealsoimagedinpractice.Atpresent,ithasbeengenerallyrecognizedthatthenanobubblesdoexist.Inrecentyears,alongwiththedeepeningresearchofnanobubbles,agrowingnumberofscholarsbelievethatthereasonofnanobubblesexistencemaybeboundaryslipinsolid-liquidinterface.Thenaseriesofrelatedstudiesonnanobubbleshaveaveryfar-reachingsignificance.Atpresent,themajorityresearchaboutnanobubblesarestillintheexplorationstage,andarenotclearenoughintheexplorationoftheirowncharacteristicsandstabilitymechanisms.Itlacksofexperimentalvalidationabouttheexistingrelationshipbetweennanobubblesandtheboundarysliplengthofsolid-liquidinterface.Firstly,thispaperstudiestherelationshipbetweenthecharacteristicparametersofthenanobubblesandexternalconditionsbasedonaccurateimagingofnanobubbles,andproposestwonewparameters:thecharacteristicsofuniformsizeanduniformdistribution,torepresentsthecharacterizationofnanobubblesitself.Andthroughtheexperimentalmeasurementsandanalysis,theaccuracyofthesetwoparametersisverified.Thenweuseahomemadecolloidalprobeexperimentstomeasurethesliplengthofthesolid-liquidinterface,andcomparetheresultswiththecalculatedvalueoftheoreticalcorrectionformulathatproposedinthispapertoprovethefeasibilityofthemodifiedformula.Finally,onthebasisoftheexperimentalphenomena,weproposethefactorsthatmayaffectthestabilitymechanismofnanobubbles,anddescribethebasisforthisspeculationindetail.Keywords:Solid-liquidinterface;Boundaryslip;Nanobubbles;Uniformity;Roughness;Temperature;目录摘要IAbstractII第1章绪论11.1课题来源11.2研究的目的及意义21.2.1研究的理论意义21.2.2纳米气泡研究的实用价值31.3国内外的研究状况41.3.1纳米气泡存在性研究41.3.2纳米气泡特征参数与外界条件间关系研究51.3.3纳米气泡特征参数与固液界面滑移长度间关系研究61.3.4纳米气泡以自发方式形成机制的研究71.3.5纳米气泡长久稳定存在机制的研究71.4主要研究内容8第2章纳米气泡特征参数测量及与外界条件的关系92.1纳米气泡的成像92.1.1样品制备92.1.2纳米气泡成像及实验参数设置102.2纳米气泡常用的表征参数172.3纳米气泡宽度均匀性172.3.1纳米气泡宽度均匀性定量评价方法的选择172.3.2纳米气泡宽度均匀性的定量评价