煤系高岭土合成al-mcm-41介孔分子筛及其催化应用-synthesis of al - mcm - 41 mesoporous molecular sieve from coal series kaolin and its catalytic application.docxVIP

crystalizationtime,2oC/minheatingrateand550oCsample’scalcinationtemperature.ThetargetproductAl-MCM-41preparedunderoptimizedconditionhad580.65m2/gBETsurfacearea,0.54cm3/gporevolume,3.57nmaverageporediameterandSi/Alatomratioof9anditexhibitedhighcrystallinityandnonuniformsphereparticles.Mostofthealuminumhadincorporatedintotheframework.ThethermalstabilityofAl-MCM-41wasstudied.Withtheincreaseofsample’scalcinationtemperature,siliconhydroxylexcessivelyshrankandtheorderedstructurepartlycollapsed.XRDresultssuggestedthatthesamplestillretainedthehighlyorderedstructureaftercalcinedat700oCfor2hours.Thestatichydrothermalstabilitywasalsoinvestigated.Theorderlinessofthesampledecreasedsignificantlyafterimpregnationintheboilingwaterfor12hours.Thissuggestedthatthesample’shydrothermalstabilityneededimproving.ThefeasibilityofAl-MCM-41usedasthesupportintheCO-PROXwasstudiedandtheinfluenceofAl-MCM-41onthecatalyst’sstructureandactivityperformancewasinvestigated.Keywords：Mesoporousmolecularsieve；Al-MCM-41；Kaolin；Carbonmonoxide；Preferentialoxidation目录引言.......................................................................................................................1第一章文献综述.........................................................................................................31.1介孔材料研究背景.............................................................................................31.1.1介孔材料制备方法......................................................................................31.1.2介孔材料合成机理......................................................................................51.1.3有序介孔材料的应用..................................................................................61.1.4MCM-41在催化领域中存在的主要问题及改进方法71.2高岭土改性及其在催化中的应用.....................................................................91.2.1高岭土简介..................................................................................................91.2.2高岭土改性及其在催化领域的应用........................................................101.3一氧化碳优先氧化催化剂研究进展.