稀土金属配合物的合成、结构及磁性分析-synthesis, structure and magnetic analysis of rare earth metal complexes.docx

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2018-08-07 发布于上海
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稀土金属配合物的合成、结构及磁性分析-synthesis, structure and magnetic analysis of rare earth metal complexes.docx

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稀土金属配合物的合成、结构及磁性分析-synthesis, structure and magnetic analysis of rare earth metal complexes

Synthesis,CrystalStructuresandMagneticPropertiesoftheLanthanide-basedCoordinationComplexesAbstractRecently,studiesonthesynthesisofpolynuclearlanthanide-basedsingle-moleculemagnetshavereceivedconsiderableattention,especiallyfortheDy3+,Tb3+,Ho3+,Er3+andYb3+ions.Toobtainlanthanideclusterswithnoveltopologies,theselectionofligandandbridgingligandisoneofthekeyfactors.Inthisthesis,thepolydentateSchiffbase2-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoicacid(H2L)hasbeenusedastheligand,becauseithasfourdifferentkindsofoxygenatomsandonenitrogenatom,andshowsvariouscoordinationmodes.Meanwhile,bychangingthereactionconditions,theligandmaybedecomposedtothetworeactants,anthranilicacidando-vanillin.Thereforethecoexistenceofthreeligandsmayleadtoagreatnumberofcomplexeswithnoveltopologiesandsuperiorproperties.Basedontheconsiderationsmentionedabove,wehavepreparedthreetypesofhigher-nuclearityhomometalliclanthanoidclusters(1-13),onetypeof3d-4f/4fsinglechaincomplexes(14-18)andtwotypesoflower-nuclearitylanthanideclusters(19-25)byalternatingthebridgingligands,pHvaluesofthereactionsystemorcombiningwiththe3dtransitionmetals.Thecrystalstructuresandmagneticpropertiesofthemhavebeenstudied.Theresultsshowedthatamongofthem,threecomplexesshowfield-inducedslowrelaxationofmagnetizationwhile1complexmayshowsinglechainmagnetproperties.Theresultsofthisthesisarebrieflysummarizedasfollows.Afamilyofnewoctanuclearlanthanidecompounds[Na2Ln6L8(C6H4NH2COO)2(C2H5OH)2(H2O)4(NO3)]?NO3?C2H5OH?nH2O[H2L=2-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoicacid;Ln=Dy(1)(n=15);Tb(2),Gd(3)(n=14);Sm(4)(n=16)]havebeenpreparedunderhydrothermalconditions.TheX-raycrystalstructureanalysisrevealsthatanitrateion,whichdisplaysanunusualμ8-η2:η2:η4tridentatebridgingmodeandbridgesalltheeightmetalions,islocatedinthecenterofthecluster.Thecoreofthestructureisa[4+2]combinationofanLn4cubaneandanLn2unit,whichisquitedifferentfrompreviouslyreportedLn6cases.英文摘要稀土金属配合物的合成、结构及磁性研究Alternatingcurrentsusceptibilitymeasurementsrevealthatt