微量sc zr对高合金化al-zn-mg-cu合金组织和性能的影响-effect of trace sc zr on microstructure and properties of highly alloyed al - zn - mg - cu alloy.docxVIP

重庆大学 重庆大学硕士学位论文 英文摘要 II II ABSTRACT Three kinds of Al-Zn-Mg-Cu alloys with different content of Sc, Zr, produced by low-frequent electromagnetic casting technology, were subjected to homogenization treatment, hot extrusion, solution and aging treatment. The tensile mechanical properties and microstructure of alloys containing different Sc, Zr were studied by using optical microscopy (OM), differential thermal analysis (DSC), scanning electron microscope (SEM), transmission electron microscope (TEM), micro Vickers hardness tester, universal testing tensile tester and conductivity tester, as well as the existing forms and acting mechanisms of minor Sc, Zr in Al-Zn-Mg-Cu alloy, optimization of the heat treatment processes. Several conclusions can be summarized as follows: ① Minor Sc, Zr addition can fine grains of alloy 3 containing 0.15% Sc and Zr, respectively, by precipitating of primary Al3(Sc,Zr) phase from the melt during solidification as heterogeneous nuclei. ② Minor Sc, Zr addition can strongly pin dislocation and subgrain boundaries, which can effectively stop recrystallization and remarkably improve the temperature of recrystallization of Al-Zn-Mg-Cu alloy during solution treatment by precipitating uniform, fine and diffuse secondary Al3(Sc,Zr) particles , coherented with the α(Al) matrix, during homogenization. ③ Secondary Al3(Sc,Zr) particles can remarkably improve tensile properties of alloy, due to strong interaction between Secondary Al3(Sc,Zr) particles and dislocation, which can consume extra energy when dislocation cut or bypassing the particles. Compared with alloy 1 without Sc and Zr, the tensile mechanical properties of alloy 3 containing 0.15% Sc and Zr, respectively, is better in any state. ④ Compare alloy 2 with alloy 3, the grain size of as-cast alloy decreases with the increase of Sc content, but having the same effect on effectively inhibiting recrystallization. Minor Sc addition can remarkably improve mechanical properties of Al-Zn-Mg-Cu-Zr