无模板剂耐酸性zsm-5沸石膜的制备及在渗透汽化脱水中的应用-preparation of acid-resistant zsm - 5 zeolite membrane without template agent and its application in pervaporation dehydration.docxVIP

万方数据 万方数据 Abstract Pervaporation is a new environmental membrane separation technology with high efficiency, low energy consumption and low investment. It is a promising process for azeotropic separation because it is not limited by the vapor-liquid equilibrium. It is widely used in the dehydration of organic matter, especially the dehydration of alcohols solvent dehydration. With high thermal stability, acid resistance, and excellent selectivity, the ZSM-5 zeolite membrane is ideal for pervaporation separation. Preparation of ZSM-5 zeolite membranes with high quality through appropriate route has become a hot spot on membrane research. In this paper, the secondary growth method was used to prepare ZSM-5 zeolite membranes on α-Al2O3 supports without using templating agents. The pervaporation performances of the membranes were evaluated in isopropanol/water system. The synthesis conditions were studied, such as the seed concentration, the number of crystallizations, the crystallization time, the molar ratio of Si/Al and the molar ratio of F/Si. Finally, the ZSM-5 zeolite membrane was successfully prepared with conditions that pre-seeding and crystallization twice, respectively, the molar ratio of Si/Al was 0.7, the molar ratio of F/Si was 0.9. The pervaporation performances of the membranes were improved by optimizing the synthesis conditions, such as the crystallization time, the seed concentration and the pre-seeding temperature. High-flux and high-selectivity ZSM-5 zeolite membrane was obtained and the flux and separation factor were 1.106 kg·m-2·h-1 and 24991, respectively. The hydrothermal stability and acid resistance of the prepared ZSM-5 membranes were studied. It was found that the separation factor of the membranes was kept above 1×104, indicating that there was a high hydrothermal stability with the membranes. In acidic solution with the pH of about 5.8, the influences of operating temperature on the pervaporation performance were studied. The results show