锌铝复合涂层的耐蚀性能及失效行为分析-corrosion resistance and failure behavior analysis of zinc-aluminum composite coating.docxVIP

护，而涂料A主要起电化学阴极保护；(2)相对于1mm划痕涂层，修复涂层A和修复涂层B浸泡初期开路电位均较低，并具有较大电荷转移电阻Rct且成逐渐增大趋势，对钢基体起到了良好的保护作用；(3)相对于修复涂层A，修复涂层B开路电位在浸泡60天稳定在-0.75V，电荷转移电阻为3.55×105Ω·cm2，中性盐雾出现红绣时间为40天，表现出更好的耐蚀性，这说明涂料B的修复效果优于涂料A。综上所述，本实验通过电化学手段对锌铝复合涂层的耐蚀性能进行了研究，探讨了锌铝涂层的破损失效行为，并尝试进行了快速破损修复，为锌铝复合涂层的实际应用提供了理论依据，对进一步提高锌铝涂层的使用寿命有重要的参考价值。关键词：锌铝涂层，耐蚀机理，划痕破损，失效IIAbstractItisindispensabletotakeprotectivemeasurestoprotectsteelsubstrate,becauseofsteeldirectlyexposedtoseawaterpronetocorrosion.Zn-Alcoating,whichisobtainedbychemicaldepositionofZn-Alliquidonthesurfaceofthemetal,isananti-corrosioncoating,anditprincipallyconsistsofzinc,aluminumflakes,andchromate.TheprotectivemechanismofZn-Alcoaingisthebarriereffectprovidedbythemetalflakeandtheaccumulationofcorrosionproducts,thesacrificialcathodicprotectionandthepassivationofchromate.Consideringthebenefitsofexcellentcorrosionresistance,heatresistance,nohydrogenembrittlement,wellpaintadhesionability,andthesimplepreparationtechnology,Zn-Alcoatingwerewidelyusedincorrosionprotectionofsteelfasteners.Basedontheexistingpreparationtechnology,futheroptimizationdesignwasmadetoestablishthebestcoatingformulationandpreparationprocessinthispaper.ThecharacrersofzincpowderonthecorrosionresistanteffectsofZn-Alcoatingwerelearned.TheresultsshowedthatZn-Alcoatingpresentedahighercorrosionresistant,andthecoatingthicknesswas10μm,possessedmorethan1500hourssaltspraytime,whenthemetalpowdercontentintheliquidwas25wt%,zincaluminumratiowas7:1.ThecoatingwhichwasgainedbyzincpowderBwasrelativelydense,hadslowerchangesofopencircuitpotential,hadalowerpotential-0.8Vafterimmersedfor60days,andpossessedhigherchargetransferresistanceRct.ThecorrosionresistanteffectofzincpowderBwasmoreoutstanding.Inordertoimprovethecorrosionresistanceofsubstratetomeetmoreharshcorrosionenvironment,thecompositecoatingwasobtainedbyaddingsherardizingcoatinginthemiddleofsubstrateandZn-Alcoating.Thecorrosion-resistanceofthecompositecoatingsystemwasstudied.Theresearchshowedthatthecompositecoatinghadlowercorrosionpotential,presentedthel