酰基硅烷化合物与γ,δ-环氧酮化合物的合成及光化学研究-synthesis and photochemical study of acyl silane compound and γ, δ - epoxy ketone compound.docxVIP

AbstractLightenergyisgreen,environmentprotective,sothestudiesonthephotochemistryisofgreatimportance,sinceasignificantroleinpromotingthedevelopmentwillbeonsomeareassuchasbiology,medicineandorganicsynthesis.Atpresent,thestudyonacylsilanesandepoxyketonesisahotareaoforganicphotochemistry.Ithasshownthatthephotolysisofacylsilanesleadstosilylandacylradicalswhichsubsequentlyreacttogivesomekindsofproducts.Thestudyingonthephoto-chemisyoftheepoxyketonesaregrowingdiversity,ononehand,carbonylexcitedphotoelectronexcitationcanoccursomereactionssuchasNorrishtypeⅠandNorrishtypeII,ontheotherhand,theexcitedethyleneoxidecompoundsbyphotoelectroncanalsogivearearrangementofopenloopresponse.Inthisthesis,theorganicsynthesisandorganicphotochemiscalreactionoftheo-etherbenzoylacylsilanesarestudied;inaddition,thisthesisalsostudiedtheorganicphotochemistryoftheγ-methyl-(γ,δ-ethyleneoxide)-aromaticcarbonylcompounds.Aroundthesetwothemes,thisthesishasfinishedthefollowingtwo-partstudy.Inthisthesis,akindoftheo-etherbenzoylacylsilaneswassynthesized,andthenthecompoundwascharacterized,andthengavetheattemptofthephotochemicalreactiontothiscompound.Thesestudiesprovidesomevaluableexperienceforthephotochemistry.Then,thisthesisfinishedtheresearchaboutthesynthesisandthecharacterizationoftheγ-methyl-(γ,δ-ethyleneoxide)-aromaticcarbonylcompounds;andthen,studiedthephoto-chemicalreactionofthecompounds,andgotthephotochemicalre-arrangementproduct;andthengavethepresumptionofthephoto-chemicalreactionmechanism;atlast,completedtheexpansionoffivephotochemicalsubstrates,andthen,studiedandcomparedtheresultsofphotochemicalreactionsofthesecompounds.Keywords:photochemistry;acylsilane;ethyleneoxide;carbonyl目录摘要..................................................................................................................IABSTRACT.........................................................................................................II第1章绪论........................................................................................