系列cuiicdii基金属-有机晶态材料的合成及性能研究-synthesis and properties of series cuiicdii metal-organic crystalline materials.docxVIP

AbstractMetal-organicframeworkmaterials(MOFs)notonlyhavetheadvantagesofbothpureinorganicandorganicmaterials,butalsohavebroadpotentialapplicationsinmanyfieldssuchasoptics,electromagnetism,gasadsorption,ionexchange,catalysis.Therefore,embarkingfromthematerialdesignsynthesisandfunctionorientation,eightnovelmetai-organiccrystallinematerialsweresuccessfullysynthesizedunderhydrothermalorsolovthermalconditionbasedon5-[2-carboxy-3-(1H-tetrazol-5-yl)-phenoxy]-isophthalicacid(H4ctpia)and3,4-di(3,5-dicarboxylphenyl)phthalicacid(H6dccpa)withdifferentrigidN-DonorligandsandCuII/CdIItransitionmetal.Thispapermainlydiscussestheirsynthesisconditions,topologies,thermostability,magneticpropertiesandcatalysis.Accordingtothedifferentselectedmetallicelements,maincontentsofthispaperareasfollows:PartOne,CuII-MOFs(1-5)havebeensuccessfullysynthesizedbasedon5-[2-carboxy-3-(1H-tetrazol-5-yl)-phenoxy]-isophthalicacid(H4ctpia)and3,4-di(3,5-dica-rboxylphenyl)phthalicacid(H6dccpa)withdifferentrigidN-Donorligands.Inthispart,wehavediscussedthecrystalstructuresandthermostabilityofMOFs1-5,themagneticpropertiesofMOFs1-4,especiallythephotocatalyticdegradationofMOF1.PartTwo,CdII-MOFs(6-8)havebeensuccessfullysynthesizedbasedon3,4-di(3,5-dicarboxylphenyl)phthalicacid(H6dccpa)withdifferentrigidN-Donorligands.Atthesametime,theirsinglecrystalstructures,topologiesandthermostabilityhavebeenstudiedindetails.Inaddition,wecangetmoreinformationwhichinfluenceonthestructuresandpropertiesofMOFsonthebasisoftheaboveresearchs.Thewholeworkinthispaperaimstoprovidesomeexperimentalandtheoreticalbasisforfurtherstudyonthemetal-organicframeworkmaterials.Keywords:Metal-organicframeworkmaterialsCuII/CdIIMagneticpropertiesPhotocatalyticactivity目录引言...............................................................................................................11绪论................................................................................................................21.1金属-有机晶态材料.................................................