钛 锆掺杂的sba-16负载的钴基费-托合成催化剂的催化性能分析-catalytic performance analysis of titanium zirconium doped sba - 16 supported cobalt-based fischer-tropsch synthesis catalyst.docxVIP

目录摘要..............................................................IABSTRACT........................................................III第一章前言.........................................................11.1费-托合成研究背景和现状.......................................11.2费-托合成催化剂...............................................21.3费-托合成反应器...............................................21.4费-托合成机理.................................................31.5费-托合成产物分布规律.........................................31.6费-托合成活性和选择性的影响因素...............................41.6.1活性组分化学态的影响......................................41.6.2载体的影响................................................61.6.3助剂的影响................................................助剂对Fe基费-托合成催化剂的影响助剂对Co基费-托合成催化剂的影响71.7中孔材料在费-托合成中的应用...................................71.8论文选题目的和研究思路........................................9第二章实验部分....................................................112.1催化剂的制备.................................................112.1.1试剂.....................................................112.1.2载体的制备...............................................112.1.3催化剂的制备.............................................112.2催化剂的表征.................................................113.1引言.........................................................143.2实验部分.....................................................143.3结果和讨论...................................................153.3.1X-射线粉末衍射（XRD）153.3.2透射电子显微镜（TEM）163.3.329Si固体核磁共振(29SisolidstateMASNMR)173.3.4N2物理吸附-脱附183.3.5电感耦合等离子体发射光谱（ICP）19钛、锆掺杂的SBA-`16负载的钴基费-托合成催化剂的催化性能的研究3.4本章小结.....................................................19第四章钛、锆掺杂的SBA-16负载钴基催化剂的催化性能研究204.1序言.........................................................204.2实验部分.....................................................204.2.1催化剂制备...............................................204.3催化剂的表征及费-托合成活性测试..............................204.4结果与讨论...................................................214.4.1X-射线粉末衍射（XRD）214.4.2N2物理吸附-脱附224.4.3透射电子显微镜（TEM）234.4.4