通过流延成型法制备平板式zrolt2gt汽车氧传感器-preparation of plate zr ol t2 gt automotive oxygen sensor by casting method.docxVIP
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通过流延成型法制备平板式zrolt2gt汽车氧传感器-preparation of plate zr ol t2 gt automotive oxygen sensor by casting method
武汉科技大学硕士学位论文 第 I}l(
逼迫流延成型法制备平植式 Zr Oz汽车氟传感器
摘擦
汽车氧传感器是电喷汽车主元催化转化必不可少的元件,而平板式氧化铅氯传感器是
…种新兴的汽车氧传感楼.本论文立足于平板式汽车氧传感器的研究、开发为主,根据相 关氧传感器的生产流雁,对汽车氧传感器的核心部伴一…YSZ 固体咆解质器件的粉体制备 技术、咆极浆料制备、丝网印刷、叠成热应工艺、烧纺工艺和氧传感器的信号检测等方面
进行了较为细致的研究.
在实验中采用了共沉淀法、水热法和南旅公司生产的 YSZ .:三种粉体,实验结果证明, 通过水热法制备的粉体的致密度要高于其它两种粉体,其流延装载 1段也比其它两种要高。 流延浆料采用改性敛汹做分散剂,在鱼泊中添加双氧水在不同条件下进行不同程度的氧化 改性,以改性鱼泊作分散剂在乙醇和二甲苯的混合洛剂中分散 ZrO,粉末,用沉降法观察其
沉积高度,检验分散效巢,并与其官分散剂做比较。最后得出分散效果比较好的条件是在 光照条件下氟化侃的改性鱼汹作分散剂,以该工嚣的改性鱼泊采用流 工艺制得了质量 较好的流延萦坯.氧传感糠的电极浆料采用了自制的和昆明费金属研究所生产的两种锦念 浆料,从导电情况来看,货合属研究所生产的要明显好于自制的锦余浆料,但它的附着力 不是很埋怨 a 最后进行了氛传感器性能检测,测试结果表明氧化铛氯传感器具有输出信号 准确和响应时间短的优良特性,基本能够满足在汽车排放系统中的应用要求。
关键词z 平板式汽车氧传感器; YSZ; 丝网印刷:电极 1 烧结:
第 u 页 式汉科技大学硕士学位论文
Making Planar Zirconia Oxygen Sensor by Tape陶佣sting
Abstract
Zirconia oxygen sensors are necessary for automobile,es仰cially which using electronic fuel j时ectíon,and planar zírconia oxygen sensors are new development. This paper is b剧创 on researches and developments of this kind of oxygen sensors. According to the relevant oxygen sensors prodωtion process,we have made theωreωmpo院ent of oxygen sensor (YSZ solid
electrolyte) by powder preparation ,electrode slurry preparatio n, screen printing,staιking hot
pressing 创d sin忧ring process ,创lωt we have detected the sigr础lofoxygen 阳刑1
In the experiment,伽ree kinds of YSZ powder have be暗n obtained by ∞precipitation
method,hydrothermal method and the 伽ird one which has been produced by Nanboωmpany.
ηle powder which is produced by hydrothermal method is bett,衍than the otherωw,and its slurry load ís high町, ωo. Modi日创 fish oil has beenωed as ùispersant in ethanol and xylene
solvent for dispersing YSZ powder. The experiment has added H202 into fish oil in order to
modify in different extent under varyingωnditio邸, and examined the effect of dispersion by measuring packed 巾ed height. In the end,the fish oil exposed in light for 9 hours has the best
dispersibility,
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