稀土镁合金微弧氧化工艺及陶瓷层性能分析-microarc oxidation process of rare earth magnesium alloy and performance analysis of ceramic coating.docxVIP

赣南师 赣南师范学院硕士学位论文 Abstract Micro-arc oxidation(MAO) is new type of surface treating technology that occurs at Al, Mg, Ti and their alloys, grows oxidation coating on original position of metal surface which can improve wear resistant, corrosion resistant and bonging strength.Therefore, MAO is one of the most prospective method of surface treatment for magnesium alloys. A gray oxidation ceramic film was prepaped by micro-arc oxidation on Mg-4Gd-3Ymm-0.5Zr magnesium alloy in the paper.The coating surface has many pores in the center of volcano-like heap, the microarc oxidation treatment obviously improved the corrosive resistance of Mg alloy. The coating surfaces and cross-sections morphology were characterized by scanning electron microscopy, phase composition and microstructure are studied by XRD and EDS analysis. The results show that there are three layers in oxidation coating, of which inner layer is dense, outer layer is loose and porous, transition layer between compact layer and porous layer in structure. The coating is mainly composed of MgO. The effect of different technical parameters on the microstructure and corrosion resistance of microarc oxidation film of Mg-4Gd-3Ymm-0.5Zr alloy treated by micro-arc technique was investigated by SEM, XRD, coating thickness gauge and electrochemical workstation etc. By one factor experiment in silicate system, thickness and properties of prepared coating of different electrolyte (include Na2SiO3, KOH, NaF and glycerol)content were studied.The results indicated coating thickness,hardness and corrosion resistance show certain orderwith electrolyte content. When Na2SiO3 6g/L, KOH 2g/L, NaF2g/L, glycerol 10ml/L, coating quality was optimize. Then on the foundation of silicate system, the effect of positive＆negative pulse voltage, pulse frequency, duty cycle, treatment time on oxidation film thickness, morpholog and properties were studied.The experiment results show the coating thickness increased, fewer pores with larger di