钛酸钡基及m型钡铁氧体吸波材料的制备及性能分析-preparation and performance analysis of barium titanate-based and m - type barium ferrite absorbing materials.docxVIP

中北大学学位论文 中北大学学位论文 Preparation and Characterization of barium titanate-based and M-type barium ferrite absorbing materials Abstract In this paper, to measure absorbing properties in the low-frequency(0-6GHZ), barium titanate composites modified with magnetic metal、rare earth metal、and conductive polymer were investigated. And doped M-type barium ferrite were also prepared, its magnetic and absorbing properties were studied. Barium titanate were prepared by sol-gel mehod, the morphology 、particle size and abosording properties characterized shows that the crystal phase of the sample was approximately single square shape, uniform size; the absorption peak of barium titanate powders is 3.8dB when the calcination temperature is 850℃. But it is also found that the absorbing properties of composites increased gradually with the ratio of nickel and cobalt reducing. When the ratio of nickel-cobalt is 1:4, the barium titanate (850℃) composites has the best performance, the absorption capacity is 6.8dB. The polypyrrole was synthesized by chemical oxidation and the barium titanate composites were prepared by physical composite method. The morphology and absorbing properties shows that the pure polypyrrole is reticular and the absorption peak of pure polypyrrole is only 1.14dB; the composites is uniform spherical and the best absorbing properties is 6.9dB when the mass ratio of 1:6;the absorbing properties of composites is enhanced with the increasing of the mass ratio of barium titanate. Barium titanate composite doped with rare earth Nb was prepared by the sol-gel method. Absorbing performance tests show that rare earth Nb-doped can greatly increase the dielectric loss materials, broadening the absorption band. When nBaTiO3: nNb is 1:0.008, the maximum absorption peak of is 29.6dB, the absorption bandwidth of is 1.6GHz. The rare earth-doped were prepared by the self-propagating combustion method, the wave-absorbing analysis showed that: rare earth-doped BaFe12O19 absorb be