4种外源添加剂对球磨机械化学法降解土壤中2,4―二氯苯酚影响.docVIP

4种外源添加剂对球磨机械化学法降解土壤中2,4―二氯苯酚影响 　　摘 要：针对球磨机械化学法降解高浓度有机氯污染土壤球磨时间长这一难题，以2，4-二氯苯酚污染土壤为降解对象，进行了外源添加剂对球磨机械化学法降解效果优化试验研究。以水平式行星球磨机为试验装置，分别考察了CaO、氧化铝、水钠锰矿和高锰酸钾4种外源添加剂对2，4-二氯苯酚降解的影响。结果表明，4种外源添加剂均能有效地缩短球磨时间，其降解率表现为：高锰酸钾（94%）CaO（84%）氧化铝（78%）水钠锰矿（75%），综合考虑规模化利用和经济效益，优化后的工艺参数为：CaO为外源添加剂，转速为400 r?min-1，球料比为4∶1，球磨0.5 h；在此工艺条件下，可使球磨时间由原来的19 h（降解率80%），缩短为0.5 h（降解率75%）。研究结果对缩短球磨机械化学法降解有机氯污染土壤时间有一定的参考价值。 　　关键词：外源添加剂；球磨机械化学法；2，4-二氯苯酚；CaO 　　中图分类号：X53 文献标识码：A DOI 编码：10.3969/j.issn.1006-6500.2018.04.011 　　Influence of Different Exogenous Additives on Degradation of Soil 2，4-Dichlorophenol by Ball Milling Mechanochemical Method 　　CHEN Dong1，2， TIAN Kaiyang2， XU Chenghua2， ZHANG Wei3， LIU Jiaqi1， ZHANG Wenyi1 　　（1.College of Environmental and Safety Engineering， Changzhou University， Changzhou， Jiangsu 213164， China； 2. First Geological Party， Jiangsu Bureau of Geology and Mineral Exploratio， Nanjing， Jiangsu 210041， China；3.Changzhou Xinbei Environmental Monitoring Station， Changzhou， Jiangsu 213160， China） 　　Abstract： Ball mill mechanochemical method could degrade the organic chlorine contaminated soil， but it need take a long time. The experiment was conducted to study the effect of exogenous additive on the degradation process using 2，4 - dichlorophenol contaminated soil as the degradation object. The effects of four kinds of exogenous additives including CaO， alumina， sodium sulphate and potassium permanganate on the degradation of 2，4 - dichlorophenol were investigated by horizontal planetary ball mill. The results showed that all the four kinds of exogenous additives could effectively shorten the milling time. The degradation efficiencies were showing as follows： potassium permanganate（94%）CaO（84%）alumina（78%）sodium silicate（75%）. Taking into account the large-scale utilization and economic benefits， the optimized process parameters were as follows： CaO was as additive， the rotation speed was 400 r?min-1， the ratio of ball to material was 4∶1， and ball milling time was 0.5 h.