丙烯论文丙烯叔丁基过氧化氢环氧化共氧化六羰基钼.docVIP

丙烯论文：丙烯 叔丁基过氧化氢 环氧化 共氧化 六羰基钼 【中文摘要】环氧丙烷是一种重要的有机中间体,是除聚丙烯和丙烯腈外的第三大丙烯衍生物。目前,全球环氧丙烷正以5%年均市场需求率不断增长,具有广阔的市场前景。环氧丙烷的工业生产方法主要有氯醇法和共氧化法两种。传统的氯醇法生产工艺存在废水产生量大,设备腐蚀严重,环境不友好等缺点;共氧化法虽然流程较长、工艺复杂,生产中对设备和原料要求较严、投资费用较高等缺点,但是由于其产物收率高,后续处理容易,污染少,联产产品收益高等特点,经济效益明显。由于以Arco工艺为代表的共氧技术专利属于国外,国内大部分企业因面临技术壁垒和安全性等问题,仍采用传统氯醇法工艺。因此,开发环境友好的丙烯共氧制备环氧丙烷工艺,具有重要的应用价值。本文以叔丁基过氧化氢为氧源,六羰基钼为催化剂催化丙烯环氧化合成环氧丙烷,首先制备六羰基钼催化剂,并用FT-IR、ICP-AES等手段对其进行了表征,同时对六羰基钼和其他钼系均相催化剂进行了评价,结果表明六羰基钼在该体系中的催化反应效果为最佳。采用高效液相色谱法测定产物中叔丁基过氧化氢的含量,在优化的色谱条件下,丙烯环氧化体系中的各组分在4min内可完全出峰,并得到良好的分离。结果表明,叔丁基过氧化氢具有良好的线性关系,线性相关系数为0.9998,回收率为99.42%～101.17%,重现性相对标准偏差为0.36%～0.52%,重复性相对标准偏差为0.79%,受酸碱性影响小。该方法精密度和准确度都较高,且分析速度快,简便,经济,是较为理想的检测分析方法。共氧化反应选取六羰基钼为催化剂,采用单因素实验,考察了催化剂浓度,反应温度,丙烯与叔丁基过氧化氢的摩尔比(烯过比),反应时间等因素对环氧化反应的影响,考察了钴盐助剂对反应的影响,并在脱水方面对工艺的优化进行了探讨。结果表明,将原料经无水硫酸镁进行脱水后,在钼质量分数为1.7×10-4,反应温度120℃ 【英文摘要】Propylene poxide is an important organic intermediates,which is the third largest derivatives of propylene besides polypropylene and acrylonitrile. Currently, the market demand of propylene poxide in the global is increasing at 5% per year. It is of great broad market prospect. There are two main industrial techniques to manufacture propylene epoxide, which are called chlorohydrin process and co-oxidation method.The traditional chlorohydrin method has mature technology,good selectivity, high yield but in production process it can bring lots of wastewater with chlorine,corrode devices and pollute environment seriously. The technology of co-oxidation has some advantages such as has little pollution , corrosion and high yield of joint products but has long flowsheet,high demand of equipment,high investment cost and can be restricted by the market of joint products.Arco process, the representative of the co-oxidation process, is developed by foreign company. At present, the majority of domestic companies are still using the traditional chlorohydrin process because of the technological barriers and s