基于萤石呈色机制探讨中国药典对紫石英色泽规定お.docVIP

基于萤石呈色机制探讨中国药典对紫石英色泽规定お 　　[摘要]紫石英?楦究瞥Ｓ靡?，用于肾阳亏虚，宫冷不孕，惊悸不安，失眠多梦，虚寒咳喘等症，自《中国药典》（1985年版）起将紫石英的来源规定为氟化物类矿物萤石族萤石，主含氟化钙（CaF2），紫色或绿色，深浅不等。市场上紫石英质量差异较大，其颜色多样，除药典规定的紫色和绿色外，白色与黄色亦为紫石英的常见颜色。通过对氟化物类矿物萤石族萤石的相关研究文献进行查阅、分析，总结了萤石的颜色及其呈色机制。天然萤石是自然界中颜色品种最多的矿物，萤石的颜色主要是混入杂质元素造成。目前关于萤石的紫色的呈色机制主要认识有：稀土离子（4fN离子），色心，包裹体，晶畴或亚显微包体呈色。萤石的绿色为Sm2+和补偿电价离子Na+所产生的色心而引起的570 nm吸收峰及305 nm吸收造成；萤石的黄色为过渡元素的加入，造成晶体离子间的电荷转移形成O2O32离子分子色核造成；萤石的黑色，主要是由于存在有演化程度较高的有机质所引起。提出了《中国药典》紫石英的性状修改建议。 　　[关键词]紫石英； 颜色； 《中国药典》； 矿物； 萤石； 呈色机制 　　Analysis of color regulation of Fluoritum in Chinese Pharmacopoeia based on 　　the coloration mechanism of Fluorite 　　HAN Ting， JIA Zhe， ZHANG Hui， LIU Huan， GAO Yan， ZHANG Ying， LIN Qinghua， XU Shuya， XU Xinfang， LI Xiangri* 　　（School of Chinese Materia Medica， Beijing University of Chinese Medicine， Beijing 100102， China） 　　[Abstract]The fluoritum is used for gynecology frequently and it′s for those diseases： kidney yang deficiency， Gong cold sterility， palpitation due to fright， insomnia and dreaminess and cold cough It′s ruled in Chinese Pharmacopoeia （1985 edition） that the fluoritum originates from fluorite which belongs to fluoride minerals Its main content is CaF2 The colors are of differents grades with purple or green In the market， there are large differences in quality and it has various colors Besides of the ruled color of purple and green， white and yellow are also common colors By digging into and analysis the relevant research literature of fluorite which belongs to fluoride minerals， colors and coloration mechanism of fluorite are summarized in this paperNatural fluorite is the mineral which has the most species of colors in nature The different colors of fluorite are mainly caused by the impurity elements At present， there are mainly about the coloration mechanism of fluorite： rare earth ions （4fN ions）， color center， inclusions， crystalline domains or sub microscopic inclusions The green of fluorite is produced by 570 nm and 305 nm absorption peaks which are c