科研毕业论文英文在前.doc

Article Chen et al 014 PAGE 2 Undergrad. Chem. Commun. 2010, 1(1), 014-015 Dept. Chem., Zhengzhou 栏目名 郑州大学标志 [journal], [year], [vol], 00–00 页码 Synthesis of new redox resin ABSTRACT The new redox resin was synthesized by phenol, hydroquinone and formaldehyde directly. Hydroquinone can be oxidized to quinine, the reversed reaction also can be achieved. The transformation between hydroquinone and quinine provides a reprod-uceible property for redox resin. Hydroquinone and formaldehyde polymerize a linear chain, but it has a poor physical character resulting from its hydrophilicity and viscosity. Phenol can catenation, then the redox resin has neither hydrophilicity nor viscosity for its three-dimensional network structure. The oxidizing and reducing ability of redox resin is expressed as the oxidizing reducing capacity. The oxidizing reducing capacity can be determined by titration. The traditional redox resin was synthesized by hydro-quinone and formaldehyde. They polymerize together and pass through the hole of net in the alkalescence anion-exchange resin, just like a snake basket model.[1] Because of the redox group not bonding with the alkalescence anion-exchange resin and the redox group eluted easily, the traditional redox resin is unendurable. The new redox resin is synthesized by phenol, hydroquinone and formaldehyde directly. Hydroquinone and formaldehyde polymerize a linear chain, but it has a poor physical character resulting from its hydrophilicity and viscosity. The reason for these is that the hydroxyl group of hydroquinone can form hydro-gen bond with water molecules, and that the linear chain structure cannot keep the resin molecule at solid state. To have a stable form, it should be combined with a cross-linking r