X80钢在红壤模拟溶液中的腐蚀行为研究-材料物理与化学专业论文.docxVIP

II II Abstract X80 steel has lots of good properties, such as, high strength, high toughness and excellent resistance to stress corrosion performance, which is widely used in transporting gas, oil. Corrosion problem has been received extensive attention, but however, the study on the cathodic process and corrosion in electrochemical thin film is seldom reported. The impact of pH and dissolved oxygen (DO) concentration on corrosion behaviors of X80 steel in simulated red solution was studied by means of potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), electrochemical noise (EN), scanning Kelvin probe and three-dimensional video microscope. The type of cathodic reaction has been achieved and mechanisms of corrosion have been investigated. The differences of corrosion rules between solution and electrochemical thin film have been analyzed. The main research results are as following: The theoretical calculation showed cathodic reaction meets the conditions for the hydrogen reduction reaction and oxygen reduction reaction, driving force of oxygen reduction reaction is greater than the hydrogen reduction. Hydrogen reduction process is verified using hydrogen collection method. Oxygen concentration of simulated red soil solution, immersed in the for 24 h, decreased from 4.29 ppm to 2.56ppm, which confirmed that oxygen has participated in the cathode reaction. Therefore, cathodic process reacted oxygen and hydrogen reduction process with different proportion. EIS under different potential was employed to study corrosion of X80 steel in simulated red soil solution at pH 4.0, the results showed that reaction was controlled by oxygen diffusion between-0.7 V potential to -0.9 V potential; when potential fell to 1.1V ~ 1.5V, it was mainly controlled by hydrogen reduction. As pH decreases, corrosion current density increases. Cathode process of X80 steel in simulated red soil solution at pH 5.5 is mainly controlled by the oxygen depolarization. X80 was