α-酮戊二酸超分子复合物的合成、结构及性质研究-物理化学专业论文.docxVIP

PAGE PAGE IV ABSTRACT oxalate and 2,2’-bipyridine. O xalate and malonic acid are in situ decomposition of α-ketoglutaric acid. The complex 11 moleculars connected each other by the hydrogen bonding and π···π stacking interactions to give a three dimensional supramolecular structure. The complex 11 was applied to the epoxidation of styrene reaction, and the catalytic results show that the complex catalyst possesses 47.2% styrene conversation and 43.6% selectivity of epoxyethylbenzene at 80 °C for 6 h. Moreover, the complex catalyst can be recycled two times without any loss of catalytic activity. Key Words: Supramolecular Complexes; α-Ketoglutaric acid; in situ decomposition; Catalytic; Bacteriostatic; 目录 目 录 目 录 HYPERLINK \l _bookmark0 第一章 绪论 ························································································ 1 HYPERLINK \l _bookmark1 1.1 超分子化学及晶体工程 ······························································· 1 HYPERLINK \l _bookmark2 1.2 配位键构筑的超分子网络结构······················································ 2 HYPERLINK \l _bookmark3 1.2.1 气体储存·········································································· 2 HYPERLINK \l _bookmark4 1.2.2 气体吸附分离 ··································································· 2 HYPERLINK \l _bookmark5 1.2.3 发光材料·········································································· 3 HYPERLINK \l _bookmark6 1.2.4 催化材料·········································································· 3 HYPERLINK \l _bookmark7 1.2.5 磁性 ················································································ 5 HYPERLINK \l _bookmark8 1.3 分子间弱作用力构筑超分子网络结构 ············································ 5 HYPERLINK \l _bookmark9 1.3.1 通过氢键构筑超分子网络结构 ············································· 5 HYPERLINK \l _bookmark10 1.3.2 π···π 堆积 7 HYPERLINK \l _bookmark11 1.3.3 范德华力·········································································· 9 HYPERLINK \l _bookmark12 1.4 超分