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三种典型污染物对超滤膜的污染研究-市政工程专业论文
哈尔滨工业大学工学硕士学位论文
哈尔滨工业大学工学硕士学位论文
万方数据
万方数据
Abstract
Water shortages and pollution are the greatest threats that we are facing with, particularly, water pollution problems is the most pressing problem that we need to resolve right now. However, the types of pollutants are increasing rapidly, and the removal of disinfection byproducts is difficult, while drinking water quality standards becomes more and more stringent. Against this background, the water treatment technology of ultrafiltration membrane stands out, but the membrane fouling hinders its extensive application. Based on previous studies, this study uses humic acid(HA), sodium alginate(SA) and bovine serum albumin(BSA) to simulate the effects of humus, polysaccharides and proteins on membrane fouling. This research only studies the effects of the concentration of pollutants, solution conditions and the admixture of different pollutants on the reversibility and resistance of membrane fouling and flux decline without considering the influences of particles, turbidity and metal ions. Flat ultrafiltration membrane was used in this research.
The experiment of single pollutant’s effects on ultrafiltration membrane investigated the retention rate and concentration of HA, SA, BSA after treatment with UF, and how the changes of solution conditions impact flux decline and the reversibility and resistance of pollution on UF. Experimental results show that: the UF membrane has high retention rates of HA, SA and BSA; Increasing concentration of HA, SA, and BSA can aggravates the pollution of ultrafiltration membranes, high concentration of pollutants can form thick cake layer on the surface of membrane and increase the pollutants which adsorbed by membrane’s internal pore; HA, BSA major causes irreversible pollution, SA mainly causes irreversible contamination; with the increasing of the pH and the concentration of Ca2+, the membrane fouling which is caused by HA, SA, BSA reduces; Na+ concentration increased so HA, BSA
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