自养护高性能混凝土抗侵蚀及收缩试验分析-experimental analysis of corrosion resistance and shrinkage of self - curing high performance concrete.docxVIP

I I 摘 要 本文针对西部干旱水资源短缺、混凝土工程严重受损和硫酸盐腐蚀问题，以及南水北调工程 远水不解近渴的现状，采用正交试验设计方法研究超吸水聚合物复合混凝土的性能，提出 28 天 龄期后混凝土自养的创新方法，为治理干旱寒冷地区水工混凝土腐蚀和冻裂难题提供理论依据。 研究的重点是在混凝土中掺入超吸水聚合物、粉煤灰、煤矸石等，深入研究各种材料单掺和复掺 后对高性能混凝土材料的力学性能、抗硫酸盐侵蚀性和收缩开裂性能产生的影响，并探讨其影响 机理。主要的研究结果有以下几方面： 1、通过正交试验，优选出的最优配比：水胶比 0.32，粉煤灰掺量 20%，煤矸石掺量 12%， 砂率 44%，SAP 掺量 0.6%，在对比试验中，表现出了良好的力学性能和耐久性能，将为耐久性 混凝土工程的施工配制提供一定的参考。 2、超吸水聚合物自养作用，使干养条件下的高性能混凝土抗压强度提高增幅为 2%，标养条 件下使抗压强度降低 8.5%，干养条件下抗压强度较标养条件下提高 6.8%，说明掺加超吸水聚合 体对干养条件下的混凝土有利。 3、抗硫酸盐侵蚀对比试验表明：经过 90 次硫酸钠溶液的干湿循环，超吸水聚合物改性的高 性能混凝土表观未发生明显变化，抗压强度降低的趋势较小；而普通混凝土表观均产生了明显的 侵蚀破坏；强度损失较大，超吸水聚合物能有效提高混凝土的抗硫酸盐侵蚀性能。 4、早期收缩对比试验表明混凝土的收缩主要发生在浇筑的早期，随着龄期的增长，收缩值 逐渐减小；复掺粉煤灰和煤矸石对于混凝土的干燥收缩有降低作用；SAP 的自养护作用能有效降 低混凝土的干燥收缩，早期降低的幅度高于后期。 关键字：高性能混凝土，超吸水聚合物，自养护混凝土，力学性能，抗硫酸盐侵蚀性能，早 期收缩 II II Abstract Aimed at western areas where the water resource is shortage, the concrete construction was seriously damaged and cracking caused by freezing and sulfate corrosion, and the state was unsolved enough timely by South-to-North Water Diversion, the paper uses orthogonal test methods study to design the performance of super-absorbent polymer concrete and presentes a new method— self-curing after 28-day date, which provides theoretical gists for solving concrete leakage and cracking caused by corrosion and freezing in chilly desert areas. The keystone is mainly focused on adding super-absorbent polymer, fly ash and coal gangue, and at the same time deeply focused on studying the mechanical properties、sulphate erosion and shrinkage cracking resistance mechanism of concrete with these materias only and compoundly, then discussesing the influence on mechanical properties、sulphate erosion and shrinkage cracking resistance of the concrete.The main research results are as follows: Determine the basic mechanical properties after orthogonal test, and came to the conclusion :the optimal ratio is 0.32 of water/cement ratio, 20% of fly ash, 12% of coal gangue , 44% of fine aggregate ratio and 0.6 % of SPA. In contrast test, the component c