6205334无机光谱化学InorganicSpectroscopic.pptVIP

6205334 無機光譜化學 Inorganic Spectroscopic Chemistry Time : Thursday 9:00 - 11:45 Classroom : Chem 430 Textbooks : ˙ F.A. Cotton “Chemical Applications of Group Theory, 3rd ed.”, 1990, Wiley. ˙ E.A.V. Ebsworth, D.W.H. Rankin, S. Cradock “Structural Methods in Inorganic Chemistry, 2nd ed.”, 1991, CRC. ˙ R.S. Drago “Physical Methods for Chemists, 2nd ed.”, 1992, Saunders. ˙ A.K. Brisdon “Inorganic Spectroscopic Methods” 1998, Oxford. Contents : ˙ UV-visible (electronic) spectroscopy Cotton Chapter 9 Ebsworth/Rankin/Cradock Chapter 6 Brisdon Chapter 4 ˙ IR/Raman (vibrational) spectroscopy Cotton Chapter 10 Ebsworth/Rankin/Cradock Chapter 5 Brisdon Chapter 2 ˙ Mass Spectrometry Ebsworth/Rankin/Cradock Chapter 9 Drago Chapter 16 Brisdon Chapter 5 ˙ NMR Spectroscopy Ebsworth/Rankin/Cradock Chapter 2 Drago Chapter 7, 8 Brisdon Chapter 3 ˙ ESR Spectroscopy Ebsworth/Rankin/Cradock Chapter 3 Drago Chapter 9 Brisdon Chapter 3 Grade : Mid-term 40% Final 40% Quiz 20% Introduction Some physical techniques in determining structure  excited state electronic transition vibrational transition rotational transition ground state E = Eelectronic + Evibration + Erotation + Etranslation population distribution Nupper ——— = exp(-DE/kT) k =1.381 ? 10-23 J/K Nlower radiation E = hu = hc/l unit 1 nm = 10-9 m 1 cm-1 = 11.98 J/mol = 2.86 cal/mol 1 eV = 96500 J/mol = 23060 cal/mol spectrum of electromagnetic radiation timescales associated with some spectroscopic techniques Energy of excited state Typical relaxation Typical Technique (Hz) time (seconds) linewidth (Hz) NMR (solution) 108 10 10-1 ESR (solution) 1010 10-5 105 rotational spectroscopy (gas) 1011 10-4 104 vibrational