土壤污染化学修复owjObc1Y.pptVIP

1. In Situ Chemical Oxidation Using KMnO4 is cheaper than the baseline pump and treat technology for certain applications, because the time of remediation can be significantly reduced by targeting treatment of zone. In Situ Chemical Oxidation Using KMnO4 can also be cheaper than alternative technologies such as deep soil mixing, as larger volumes of soil can be treated with multiple oxidant dosings. * 2. In Situ Chemical Oxidation Using KMnO4 is advantageous over the baseline and alternative technologies because it generates innocuous by-products (carbon dioxide and manganese dioxide solids), allows introduction of large volumes of oxidant solution; the recirculation process provides for better oxidant control within the treatment area as compared to well injection alone. * * 臭氧（O3） O3作为原位化学氧化技术的氧化剂的优点： 分散能力高于其他液态氧化剂； 采用原位氧化时，比生物降解或土壤排气过程更快，因此，减少修复时间和处理费用。 * 4.原位化学还原与脱氯修复技术 4.1 原位化学还原与脱氯修复技术（in-situ chemical reduction and reductive dehalogenation remediation） 对地下水构成污染的污染物经常在地面以下较深的范围内，在很大的区域内呈斑块状扩散，这使得常规的修复技术往往难以奏效。一个好的方法是创建一个化学活性反应区或反应墙，当污染物通过这个特殊区域的时候被降解或固定，即原位化学还原与脱氯修复技术。 * 原位化学还原与脱氯修复技术是利用化学还原剂将污染物还原为难溶态，从而使污染物在土壤环境中迁移性和生物可利用性降低。 还原剂包括液态、气态和胶体还原剂 污染土壤的原位化学还原修复处理过程主要涉及3个阶段：注射、反应以及将试剂与反应产物抽提出来。 * * * * * 4.2原位化学可渗透反应处理墙 4.2.1 可渗透反应墙：Permeable Reactive Barriers (PRB)：是一种由被动反应材料构成的物理墙，通过挖掘来建造，然后进行重新定位，墙体是由天然物质和一种或几种活性物质混合在一起构成的。当污染物沿地下水流向迁移，流经处理墙时，它们与墙中的活性物质相遇，导致污染物被降解或原位固定。 * Permeable Reactive Barriers are passive in situ treatment zones of reactive material that degrades or immobilizes contaminants as ground water flows through it. PRBs are installed as permanent, semi-permanent, or replaceable units across the flow path of a contaminant plume. Natural gradients transport contaminants through strategically placed treatment media. The media degrade, sorb, precipitate, or remove chlorinated solvents, metals, radionuclides, and other pollutants. * * GW DNAPL plume Aquitard contamination source heavy metals Aquifer LNAPL reactive barrier cl