基于响应面法的木质素炭制备工艺优化-中南林业科技大学学报.PDF

第37 卷 第8 期 中南林业科技大学学报 Vol. 37 No. 8 2017 年8 月 Journal of Central South University of Forestry Technology Aug. 2017 Doi:10.14067/ki.1673-923x.2017.08.019 http: // 基于响应面法的木质素炭制备工艺优化 张新荔，吴义强，胡云楚 （中南林业科技大学 材料科学与工程学院，湖南 长沙 410004 ） 摘 要：为开发生物质导电材料，以木质素为原料，氯化铁为催化剂，通过热解炭化工艺制备木质素炭，并利用 响应面法对影响炭产率的4 个主要因素即载气流量、升温速率、炭化温度、炭化时间进行了优化。研究结果表明， 利用 Design-Expert 软件的 Box-Behnken 设计建立的二次多项式模型较显著，当载气流量为 1.26 L/min，升温速率 为20 ℃/min ，炭化温度为700 ℃，炭化时间为60 min 时，炭产率达到最大值46.04%，与实际值45.86% 较为接近， 说明优化结果可信。洗涤处理后的木质素炭呈片层堆积状，其结构类似于石墨微晶炭，电阻率为 0.353 Ω·cm。 关键词：木质素；炭化；电阻率；响应面 中图分类号：S718.39；TQ424.1 文献标志码：A 文章编号：1673-923X(2017)08-0114-08 Optimization of preparation conditions of lignin based conductive char using response surface methodology ZHANG Xinli, WU Yiqiang, HU Yunchu (College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, Hunan, China) Abstract: In order to produce biomass conductive materials, a kind of conductive charcoal was prepared by pyrolysis carbonization of lignin with ferric chloride as catalyst. Four main factors affecting the yield of charcoal, namely the flow rate of carrier gas, heating rate, carbonization temperature, and time were optimized by response surface methodology. Experimental results showed that the quadratic polynomial model based on the Box-Bohnken design of Design Expert software was significant, the maximum yield of charcoal was 46.04% at the carrier gas flow rate of 1.26 L/min, heating rate of 20 ℃/min, carbonization temperature of 700 ℃ , and carbonization time at 60 min, which was close to the actual yield of 45.86%, indicating the