重金属在不同粒径PM10中的含量与形态-地球科学与环境学报.PDFVIP

28 4 Vol . 2 8 No . 4 2 0 0 6 12 　Journal of Earth Sciences and Environment 　 Dec. 2 0 0 6 PM10 1 1, 2 1, 2 戴塔根 , 罗莹华 , 梁　凯 (1. , 410083;2. , 512005) [] 　WYX 402A Tessler Cu、Pb、Zn、Cd、Cr、As PM 10 。 Cu、Pb、Cd、As ,Zn、Cr 1. 1～2.0μm , 。 , 。, Cu ;Pb ;Zn ;Cd , ;Cr , , ;As 3 , , 。 [] 　;;; [] 　X132　[]　A 　[] 　1672-6561(2006)04-008-7 05 Contents and Form of Heavy Metal in PM10 of Different Diameters 1 1, 2 1,2 DAI Ta-gen , LUO Ying-hua , LIANG Kai (1. School of Geolog y an d Env i ronment E ng i neer ing , Cen tra l S outh Univ ersi ty , Chang sh a 410083, H unan, Chi na;2. D ep art ment of Tourism, S haoguan Uni versi ty , S haoguan 512005, Guang dong, Chi na) Abstract:The WYX-402A atomic absorption spectrometry and Tessler scheme are used to study contents and activity of Cu, Pb, Zn, Cd, Cr and As in PM 10 of different diameters. The results indicate that contents of Cu, Pb, Cd and As increase with the decrease of diameters;contents of Zn and Cr increase with decrease of diameters in despite of the max-i mum within the diameter range 1. 1μm to 2.0μm. The activity of heavy metals is different in PM 10, that is, activity of Cu increase with the decrease of diameters, activity of Pb is stable, activity of Zn fall when diameters decrease. The dominant form of Cd is carbonate and oxides and its activity is bigger in fine particles. The dominant form of Cr is oxides and residual, and its activity is stable in particles of different size. Soluble, carbonate and oxides are the main form of As, and its activity fall w hen diameters increase in the stable environment. Key wo