熔盐电解法制备铝锂中间合金.PDFVIP

18 8 2008 8 Vol.18 No.8 The Chinese Journal of Nonferrous Metals Aug.. 2008 1004-0609(2008)08-1555-05 ( 110004) LiCl-LiF-Li CO 2 3 Li CO LiCl 2 3 Li CO 2 3 2%Li CO 0.5 V 2 3 2 15 min680 0.62 A/cm 3 h 7.93%74.1% TF 827.2 A Preparation of Al-Li master alloys by molten salt electrolysis LI Ji-dong, ZHANG Ming-jie, ZHANG Ting-an, LI Dan, ZHANG Zhuo (School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China) Abstract: Al-Li master alloys were prepared using sinking-mode aluminum liquid as cathode and a mixture of LiCl-LiF-Li CO as molten salt electrolyte in a laboratory cell. The electrolysis process with Li CO as raw material 2 3 2 3 instead of LiCl was studied in detail. The technological parameters such as back electromotive force, cell voltage, current and electrolysis waveform were measured by testing device of molten salt electrolysis. The period of Li CO feeding was 2 3 adjusted by the method of electric potential control. At the same time, the factor that affects current efficiency was discussed according to the lithium content of alloys obtained. The results indicate that back electromotive force increases with increasing current density and decreases by