（毕业学术论文设计）-以TiO2为涂层选择性催化还原氮氧化物催化剂制备.doc

以TiO2为涂层选择性催化还原 氮氧化物催化剂制备 摘要 氮氧化物(NOx)是大气的首要污染物之一，对人体健康和生态环境具有严重危害。中国的NOx排放量不断增加，氮氧化物的污染控制和治理迫在眉睫。选择性催化还原(SCR)技术由于具有高效率、高选择性和高经济性，成为NOx治理的主流技术之一。 本论文以SCR技术的核心问题即催化剂为研究对象，制备选择性催化还原氮氧化物催化剂。以堇青石蜂窝陶瓷为基体，采用溶胶-凝胶法负载TiO2涂层和浸渍法负载活性组分V2O5和WO3，制成具有一定活性的选择性催化还原NOx催化剂。以NH3选择性催化还原NO为模型反应，研究不同TiO2涂层负载量、V2O5和WO3配比、不同的焙烧温度对催化活性的影响以及不同的反应温度、空速及氨氮比对催化活性的影响。实验结果表明，当TiO2涂层负载量为15%时，NO去除率可以达到最大。V2O5-WO3/TiO2催化剂中活性组分最佳负载量为8%，V、W最佳配比为2:10。TiO2涂层和活性组分的最佳焙烧温度分别为500℃和600℃。在最佳制备条件下反应得出，最佳反应温度区间为275℃~375℃。进料气中最佳氨氮比为1：1。低温下，NO去除率随空速的减小的而增大；高温下，NO去除率随空速的减小而减小。 关键词：氮氧化物 选择性催化还原 TiO2涂层 V2O5-WO3/TiO2催化剂 Reparation on the Catalyst Of Selective Catalytic Reduction of NOx with TiO2 as Coating Abstract Nitrogen oxide(NOx) is one of the main Pollutants in atmosphere. It does harm to human health and enviroment seriously. The amount of the NOx discharging is getting more and more. So it is a great of urgency to control the NOx Pollution. Due to high efficiency, selection and economic value, selective catalytic reduction(SCR) is one technology for NOx control. The objective of this paper focuses on the catalyst which is the key question of SCR technology. Cordierite honeycomb ceramics as base body, The sol-gel method was adopted to load TiO2 and the dipping method to load V2O5 and WO3. Selective catalyst reduction (SCR) of NO with NH3 was used as model reaction. By testing the influence of the parameters on SCR in the cource of catalyst preparation and the effect of reaction. It was found that when the loading amount of TiO2 was 15 percent can be covered completely. The most optimum amount of V2O5-WO3/TiO2 catalyst is 8 percent, V、W ratio of 2:10. The most optimum calcination temperature of TiO2 and active composition was 500℃ and 600℃. Reaction on the optimum condition of preparation, the result showed that the most optimum temperature window was in the temperature range of 275~375℃. The best NH3/NO radio was 1:1. The NO conversion would increased with the reduce of the space velocity in the low te