摘要本研究主要目的为以液态薄膜自琥珀酸水溶液中提取目的产物.DOCVIP

PAGE \* MERGEFORMAT3 摘要 　　本研究主要目的為以液態薄膜自琥珀酸水溶液中提取目的產物琥珀酸；為了加強液態薄膜在操作上的穩定性，以支撐型液態薄膜為發想，使用聚乙烯醇(polyvinyl alcohol，PVA)薄膜作為分隔板，除了將液態膜定型外，另一方面也確保液態薄膜與發酵液各自隔絕不互相影響。本研究大致分為三個部分：首先將進行縮甲醛反應以加強PVA薄膜耐用程度，調整不同甲醛溶液添加量來控制PVA縮甲醛程度，也對PVA薄膜在成膜過程、厚度、膨潤度、催化劑以及造孔進行討論。 　　第二部分則以不同含量載體三正辛胺(trioctylamine，TOA)的液態薄膜分別對不同濃度之琥珀酸溶液做靜態飽和萃取實驗，探討彼此相平衡關係。接下來則使用不同縮甲醛程度之PVA薄膜配合不同含量載體之液態薄膜對模擬發酵液進行提取實驗；並以有別於以往的夾持方式組合操作對於琥珀酸進料濃度及液態薄膜的厚度做改變，探討琥珀酸通量變化，藉由得到的平均總通量分析萃取琥珀酸時的阻力。 　　最後對液態薄膜搭配特定縮甲醛程度之PVA薄膜時有良好通量之特徵，以量測接觸角的方式探討液態薄膜與PVA薄膜間的親和性。 關鍵詞：琥珀酸、聚乙烯醇、甲醛、液態膜、三正辛胺 Abstract 　　The main purpose of this research is to extract the succinic acid by a liquid membrane from the aqueous solution. To strengthen the stability of the liquid membrane in operation, the system of supported liquid membrane is adpoted. And crosslinked polyvinyl alcohol film is used as a separator plate to ensure that the liquid membrane is isolated from the aqueous solution. This study is divided into three parts. The first part is focused on crosslinking of the PVA film by acid catalyzed formaldehyde to enhance the durability of the film. Different concentrations of formaldehyde solution were added to control the degree of crosslinking. Thickness, degree of swelling,the amount of catalyst addition and pore formation in the film forming process were discussed. 　　The second part is about the study of phase equilibrium of the extractant phase and water phase. Different concentrations of TOA in the octanol were used to extraction succinic acid from its aquous solution of different concentrations to explore that the distribution of the acid in the two PVA films of different degree of crosslinking were coupled with liquid membranes of different contents of the carrier to perform the extraction experiments. The effects of the concentration of feed phase and the thickness of liquid membrane on the succinic acid flux were explored. The analysis of average total flux analysis leading to the extraction resistance was discussed. 　　Finally measuremen