常温常压紫外催化湿式氧化降解苯酚均相催化剂的研究市政工程专业论文.docxVIP

哈尔 哈尔滨工业大学工学硕士学位论文 - -II- Abstract As for its wide source and toxicity, phenolic wastewater has always been the research focus in industrial wastewater treatment.At present, catalytic wet oxidation process is commonly used to treat phenolic wastewater in industry. Catalytic wet oxidation process has reached the level of industrial application in foreign countries such as Japan, Europe and America, but in China, it is just in the initial stage. At nomal temperature and pressure, this paper introduced UV into catalytic wet oxidation process system to treat phenol, used hydrogen peroxide as the oxidant, selected the optium homogeneous catalysts for the system and did the further research of their affecting factors,summarized their laws of the catalytic. The thesis through the comprehensive contrast of Fe2+,Mn2+,Cu2+,Ni2+,Cr3+, Co2+,Pb2+ ,the seven metallic catalysts’ effect of the degradation of phenol wastewater under three different pH level (pH=3, pH not adjusted, pH=11),indicated that Fe2+,Cu2+, Mn2+,Ni2+have the better catalytic effect. The thesis researched on the terms of oxidant and catalyst concentration and found that, within the right range, the increasing of the concentration of oxidant and catalyst could increase the catalystic reaction rate and the removal efficiency of phenol’s COD. But excess concentration of the concentration would make the catalytic system be inhibited.The suitable oxidant and catalyst concentrations of the four metals were as follows:Fe2+:H2O2=0.29mol/L,Fe2+=5mmol/L;Cu2+:H2O2=0.29 mol/L,Cu2+=8mmol/L;Mn2+: H2O2=0.24mol/L, Mn2+=12.0mmol/L; Ni2+: H2O2=0.29 mol/L, Ni2+=7.6mmol/L. The thesis discussed the reaction’s initial pH that, due to the product of the organic acids during the catalytic reaction, the catalytic effect of Fe2+ had a little change within the initial pH range of 3 to 9; the catalytic activity of Cu2+, Mn2+, Ni2+in acidic condition was significantly higher than in alkaline condition; when the initial pH was 11, the