掺稀土钇钪铝石榴石激光陶瓷材料的制备与性能研究-化学专业论文.docxVIP

I I 摘 要 采用溶胶-凝胶燃烧法和共沉淀法制备 Yb:YSAG 和 Er,Yb:YSAG 激光陶瓷粉体， 采用冷等静压与真空烧结相结合的工艺制备 Yb:YSAG 透明陶瓷。探究最佳工艺时， 制备 Yb:YSAG 样品选择 Yb3+摩尔掺杂浓度 2%；Er,Yb:YSAG 样品选择 Yb3+和 Er3+ 摩尔掺杂浓度分别为 3%和 1%。溶胶-凝胶燃烧法制备粉体的最佳工艺为：煅烧温度 950℃；煅烧时间 2h；分散剂（PEG）分子量为 10000；pH=2.5。共沉淀法制备粉体 的最佳工艺为：煅烧时间 1000℃；煅烧时间 2h；沉淀干燥时间 21h；pH=7。冷等静 压-真空烧结法制备 Yb:YSAG 透明陶瓷的工艺：终温 1750℃保温 20h，1400℃流动空 气气氛下保温 20h，得到陶瓷的平均透过率在 43%左右。 测试了粉体的结构和光谱性能，结果证明：Yb:YSAG 和 Er,Yb:YSAG 样品符合 钇钪铝石榴石的结构；Yb:YSAG 样品的最强荧光发射峰在 1032nm 处，对应 Yb3+的 2F5/2→2F7/2 能级跃迁；Er,Yb:YSAG 样品的最强荧光发射峰在 1549nm 处，对应 Er3+ 的 4I13/2→4I15/2 能级跃迁。测试了不同掺杂浓度的 Er,Yb:YSAG 样品的上转换光谱，得 出较高浓度掺杂发光依然较强，得到红光和绿光且分析了上转换机制。 关键词：Yb:YSAG Er,Yb:YSAG 溶胶-凝胶燃烧法 共沉淀法 光谱性能 II II ABSTRACT Yb:YSAG and Er,Yb:YSAG laser ceramic powders were prepared by sol-gel combustion method and co-precipitation method. YSAG transparent ceramics were prepared by cold isostatic pressing and vacuum sintering technology. The mole fraction of Yb3+ was 2% in Yb:YSAG. The mole fraction of Yb3+, Er3+ was 3% and 1% in Er,Yb:YSAG. The optimum preparation conditions for sol-gel combustion method as follows: calcination temperature was 950℃, acting time was 2h, dispersing agent (PEG) molecular weight was 10000 and pH=2.5. The optimum preparation conditions for co-precipitation method as follows: calcination temperature was 1000℃, acting time was 2h, sedimentation drying time was 21h and pH=7. The optimum preparation conditions for cold isostatic pressing-vacuum sintering method of Yb:YSAG were: temperature at 1750℃ holding 20h, temperature at 1400℃ under flowing air for insulation 20h. The average transmittance of as-prepared ceramic was about 43%. The properties of the powders have been characterized. The results proved that the structure of Yb:YSAG and Er,Yb:YSAG samples was consistent with that of yttrium scandium aluminum garnet. The fluorescent spectra showed that strongest emission peak of Yb:YSAG was at 1032nm, corresponding to 2F5/2→2F7/2 level transitions of Yb3+, and strongest emission peak of Er,Yb:YSAG was at 1549nm