多臂结构材料的端基功能化及其有机电致发光和激光器件-光学专业论文.docx

万方数据 万方数据 Abstract Development of new structure, excellent performance organic optoelectronic materials is one of the important ways to solve the bottleneck of the organic electroluminescent and organic laser field, which is of great scientific and practical significance. Multi-armed structure of organic photoelectrical materials designed by our group in previous studies achieved good device performance. In addition, a large number of studies have shown that the benzene cyano end groups greatly facilitate electron injection/transport capability. In order to improve the efficiency of the device, we put forward the design thought that using the benzene cyano as an end group to modify the multi-armed structural materials. So we synthesized a series of star-shaped molecules, four-armed monodisperse fluorene-pyrene derivatives, six-armed monodisperse fluorene-truxene derivatives and three-armed monodisperse fluorene-triazatruxene. The four-armed monodisperse macromolecules had shown good thermal stability and amorphous morphology. This series of molecules as emitting layer electroluminescent devices were prepared to obtain the relevant parameters of luminescent properties, and compare the relationship between them. The double-layer devices were fabricated with the configuration of ITO/PEDOT: PSS (40 nm)/ T1-T3 (80 nm)/1, 3, 5-tris (N-phenylbenzimidazol-2-yl)-benzene (TPBI) (40 nm)/LiF (0.5 nm)/Al (100 nm). The best EL performance is achieved by T1 with a maximum current efficiency η c, max of 3.52 cd A-1, and a maximum brightness (Lmax) of 9194 cd m-2. Due to its better morphology stability, T1-T3 were studied for optically pumped laser emission.the ASE threshold (Eth) was 30 nJ pulse-1, 36 nJ pulse-1 and 34 nJ pulse-1 at 25 oC, respectively. The six-armed monodisperse macromolecules also had shown good thermal stability and amorphous morphology. This series of molecules as emitting layer electroluminescent devices were prepared, but the performance was not satisfactory.