材料热力学练习三各种热力学性质的计算.docVIP

新型材料设计及其热力学与动力学 The excess Gibbs energies of bcc solid solution of (Fe,Cr) and fcc solid solution of (Fe,Cr) is represented by the following expressions: Gex(bcc)/J＝xCrxFe (25104－11.7152T); Gex(fcc)/J＝xCrxFe (13108－31.823T＋2.748T logeT) For the bcc phase, please do the following calculations using one calculator. Calculate the partial Gibbs energy expressions for Fe and Cr Plot the integral and partial Gibbs energies as a function of composition at 873 K Plot the activities (aCr and aFe) as a function of composition at 873K What are the Henry’s law constants for Fe and Cr? For the fcc pha